Synthesis of New Type of Macrocyclic Lactones Functionalized with Different Groups and Investigation of Their Metal Binding Abilities

• Autorzy: Ertul S. , Bayrakci M.
• Języki publikacji: EN

Abstrakty

EN

New type of macrocyclic lactones functionalized with different groups were synthesized by reaction of the dihydroxy compounds such as 5a-d with suitable glycolyl chloride such as tri, tetra dicarboxylic acid dichloride derivatives. Their metal complexes with NaClO4źH2O, KClO4 and Ba(ClO4)2źH2O were studied. Furthermore, their metal-pic rate extraction studies with metal salts such as Na+, K+, Cu2+, Ni2+ and Hg2+ from aqueous phase to organic phase were attempted. All the structures of the ligands and complexes were confirmed by 1H-, 13C-NMR, IR, UV-Vis, MS and elemental analyses methods.

Słowa kluczowe

EN

macrocyclic ligand; lactone; metal-picrate extraction; Schotten-Baumann reaction

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2009
• Tom: Vol. 83, nr 3
• Strony: 493--502
• Opis fizyczny: Bibliogr. 26 poz., rys.

Twórcy

autor

Ertul S.

autor

Bayrakci M.

• Department of Chemistry, Faculty of Science and Arts, University of Selçuk, Konya, Turkey,

Bibliografia

• 1. Pedersen C.J., J. Am. Chem. Soc., 89, 2495 (1967).
• 2. Toruń L., Robison T.W., Krzykawski J., Purkiss D. W. and Bartsch R.A., Tetrahedron, 61,8345 (2005).
• 3. Liu Y., Hań J.-R. and Zhang H.-Y, Supramol. Chem., 16 247 (2004).
• 4. Junk P.C. and Steed J.W., J. Coord. Chem., 60, 1017 (2007).
• 5. Berlin A., Zotti G., Zecchin S. and Schiavon G., Synthetic Met., 131, 149 (2002).
• 6. Aghaie H., Giahi M., Monajjemi M., Arvand M., Nafissi G.H. and Aghaie M., Sensors and Actuat. B, Chem., 107, 756(2005).
• 7. Mohapatra P.K., Lakshmi D.S., Mohan D. and Manchanda V.K., J. Membrane Set., 232, 133 (2004).
• 8. Blair T.L., Cynkowski T. and Bachas L.G., Anal. Chem., 65, 945 (1993).
• 9. Lee M., Oh S.Y, Pathak T.S., Paengl .R., ChoB.Y and Paeng K.J., J. Chromatogr. A, 1160,340 (2007).
• 10. Kudo Y, Usami J., Katsuta S. and Takeda Y, Talanta, 59, 1213 (2003).
• 11. Çakir Ü.., Özer M., Içen M.A., Ugras H.A. and Bulut M., Dyes Pigments, 60, 177 (2004).
• 12. Atamas L.I., Kotlyar S.A., Grigorash R.Ya., Pluzhnik-Gladyr S.M., Shishkin O.V., Shishkina S.V.R., Zubatyuk L, Kalchenko V.I. and Kamalov G.L., J. Struct. Chem., 46, 9 (2005).
• 13. Majerski K.M. and Ramljak T.S., Tetrahedron, 58, 4893 (2002).
• 14. Szczygelska-Tao J., Biernat J.F., Kravtsov V.C. and Simonov V.A., Tetrahedron, 55, 8433 (1999).
• 15. Jia X., Zhu W., Zhang Y and Yan X., J. Mol. Struct., 604, 159 (2002).
• 16. Liu Y, Zhang Y, Bai X., Wada T. and Inoue Y, J. Org. Chem., 65, 7105 (1999).
• 17. SezginM., Bedük A.D., Ertul §. andKogak A.,Synth. React. Inorg. Met.-Org. Chem., 23,269 (l993).
• 18. Gutsche C.D. and Hyung N.-K., J. Org. Chem., 47, 2708 (1982).
• 19. Weber E., Crown Ethers and Analogs, John Wiley and Sons Ltd., New York, 1989.
• 20. Bradshaw J.S., Maas G.E., Izatt R.M. and Christensen J.J., Chem. Reviews, 79, 37 (1979).
• 21. Cox B.G. and Schneider H., Coordination and Transport Properties of Macrocyclic Compound in Solution, Elsevier Publishing Co., NY, 1992.
• 22. Kiliç Z., The Synthesis of Some New Macrocyclic Ligands and Their Complexes and Investigation of Their Structures, Ph. D. Thesis, University of Ankara, Faculty of Science, Department of Chemistry, Ankara, 1983.
• 23. Hayvali Z. and Vardimci D., Transit. Met. Chem., 33, 421 (2008).
• 24. Vicente M., Lodeiro C., Adams H., Bastida R., Blas A., Fenton D.E., Macias A., Rodriguez A. and Rodriguez-Blas T., Eur. J. Inorg. Chem., 1015 (2000).
• 25. Chabanel M., Legoff D. and Touaj K., J. Chem. Soc., Faraday Trans., 92, 4199 (1996).
• 26. Pearson R.G., Hard and Soft Acids and Bases Princible in Inorganic Chemistry, Academic Press, NY, 1977.