Alfa-Pyridoin Tautomerism - Reducing Difference Infrared Spectral Analysis

• Autorzy: Chapkanov A. , Zareva S.
• Języki publikacji: EN

Abstrakty

EN

The existence of diol and oxidized diketoforms in chloroform of -pyridoin was established using reducing-difference IR-spectral analysis for non-polarized spectra interpretation. The linear-dichroic IR-spectral analysis of the compound, studied in nematic liquid crystal solution, showed stabilization of the diolic tautomer. Detailed vibrational assignment of the corresponding modes was carried out using reduced-difference procedure for polarized spectra interpretation. The experimental results were completed and enlarged with theoretical ab initio calculations.

Słowa kluczowe

EN

alfa-pyridoin; reducing-difference IR-spectral analysis; IR-LD; tautomerism

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2009
• Tom: Vol. 83, nr 3
• Strony: 467--476
• Opis fizyczny: Bibliogr. 23 poz., rys.

Twórcy

autor

Chapkanov A.

autor

Zareva S.

• South-West University "Neofit Rilski", Department of Chemistry, 66 "I. Mihailov" str., 2700 Blagoevgrad, Bulgaria,

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