Crystal Structure and Third-Order Non-Linear Optical Property of a Novel Three-Dimensional Supramolecular Network Compound of Co(II)

• Autorzy: Li Y. , Zhang Z. X. , Wu Z. X. , Li K. C. , Li Q. S.
• Języki publikacji: EN

Abstrakty

EN

A new metal-organic complex formulated as [Co(ISOIN)2(H2O)4] 1 (H2ISOIN) = isonicotinic acid) has been synthesized by low-temperature solid-state reaction and characterized by single-crystal X-ray diffraction, elemental analyses, IR and UV-visible spectra. The strong intermolecular O-Hź ź źO hydrogen-bonds interactions are the most significant factors controlling the novel supramolecular sheet fashion packing of the title compound in the crystal state. The third-order non-linear optical (NLO) properties of 1 were also investigated and they exhibit the reverse saturable absorption and self-defocusing performance with modulus of the hyperpolarizability gamma 8.75×10-31 esu for 1 in a 1.56×10-4 molźdm-3 DMF solution.

Słowa kluczowe

EN

hydrogen bonds; isonicotinic acid; third-order NLO behavior

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2009
• Tom: Vol. 83, nr 3
• Strony: 373--381
• Opis fizyczny: Bibliogr. 35 poz., rys.

Twórcy

autor

Li Y.

autor

Zhang Z. X.

autor

Wu Z. X.

autor

Li K. C.

autor

Li Q. S.

• College of Science, Guangdong Ocean University, Zhanjiang 524088, P.R. China Tel.: [phone],

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