Magnetic Properties of Novel One-Dimensional Ni(II) Chain and Binuclear Cu(II)-Ni(II) Complexes

• Autorzy: Ren S. , Ma S. L.
• Języki publikacji: EN

Abstrakty

EN

A novel one-dimensional chain with nickel(II) macrocyclic complex and extended terephthalato-bridged, namely, [Ni(L)(TPHA)]ź8H2O (1) (L = 1,3,6,9,11,14- hexaaza-tricyclo[12.2.1.16,9]octadecane, TPHA = terephthalate dianion) and a new binuclear Cu(II)-Ni(II) complex, [Cu(oxap)Ni(bpy)2](ClO4)2ź2H2O (2) [oxap = N,N?- bis(2-aminopropyl)oxamido dianion, bpy = 2,2?-bipyridine] have been magnetically characterized by variable-temperature magnetic susceptibilities measurements. The fitting results of the agnetic data of all two complexes support exhibiting the occurrence of an antiferromagnetic coupling with J values of -1.25 cm-1 for 1 and -93.9 cm-1 for 2, respectively.

Słowa kluczowe

EN

complexes; terephthalato- and oxamido bridges; magnetic properties; macrocyclic complex

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2009
• Tom: Vol. 83, nr 2
• Strony: 181--186
• Opis fizyczny: bibliogr. 16 poz., rys.

Twórcy

autor

Ren S.

autor

Ma S. L.

• Department of Application Chemistry, College of Science, Tianjin University of Commerce, Tianjin, 300134, People's Republic of China Tel.: [phone],

Bibliografia

• 1. Ouahab L., Chem. Mater., 9, 1909 (1997).
• 2. Braga D., Grepioni F. and Orpen A.G. (Eds), Crystal Engineering: from Molecules and Crystals to Materials, Kluwer Academic Publishers, Dordrecht (1999).
• 3. Cano J., DeMunno G., Sanz J.L., Ruiz R., Faus J., Lloret F., Julve M. and Caneschi A., J. Chem. Soc. Dalton Trans., 1915(1997).
• 4. Groeneman R.H., MacGillivray L.R. and Atwood J.L., Inorg. Chem., 38, 208 (1999).
• 5. Yang R, Chen X., Ren S. and Ma S.L., Struct. Chem., 19, 291 (2008).
• 6. Suh M.P., Shin W., Kang S.G., Lah M.S. and Chung T.M., Inorg. Chem., 28, 1602 (1989).
• 7. Ma S.L., Liang Z.H., Liao D.Z., Yan S.P. and Wang G.L., Polyhedron, 12, 1523 (1993).
• 8. Geary W.J., Coord. Chem. Rev., 7, 81 (1971).
• 9. Ojima H. and Nonoyama K., Coord. Chem. Rev., 92, 85 (1988).
• 10. Rosenthal M.R., J. Chem. Educ., 50, 331 (1973).
• 11. Liao D.Z., Li L.C., JiangZ.H., Yan S.P., Cheng P. and Wang G.L., Transit. Met. Chem., 17,356 (l992).
• 12. Fisher M.E., Am. J. Phys., 31, 343 (1964).
• 13. Choi K.Y, Chun K.M., Lee K.C. and Kim J., Polyhedron, 21, 1913 (2002).
• 14. Choi K.Y, Chun K.M. and Suh I.H., Polyhedron, 20, 57 (2001).
• 15. Sinn E. and Harris C.M., Coord. Chem. Rev., 4, 391 (1969).
• 16. Badarau M., Rerat M., Kahn O., Jaud J. and Galy J., Inorg. Chem., 21, 3050 (1982).