Vanadium-containing Mesoporous Molecular Sieves: Synthesis, Properties and Catalytic Performance in Oxidative Activation of Light Alkanes

Cortés Corberán, V.; Sulikowski, B.

Artykuł - szczegóły

Tytuł artykułu

Vanadium-containing Mesoporous Molecular Sieves: Synthesis, Properties and Catalytic Performance in Oxidative Activation of Light Alkanes

Autorzy

Cortés Corberán V. , Sulikowski B.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

Vanadium-containing mesoporous molecular sieves (MMS) are quasi-crystalline solids with interesting catalytic properties in the oxidative activation of light alkanes. In the present work, the methods of their synthesis, physico-chemical properties and catalytic behaviour in the oxidative dehydrogenation and selective oxidation of C2-C4 alkanes are reviewed. It is concluded that, as with conventional supported vanadium contacts, the catalytic performance in these reactions is related to the number and environment of vanadium centres, and the best selectivity and yield are obtained over isolated vanadium sites exhibiting tetrahedral coordination.

Słowa kluczowe

mesoporous molecular sieves vanadium MCM-41 MCM-48 SBA-15 catalytic properties alkane activation selective oxidation oxidative dehydrogenation

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2008

Tom

Vol. 82, nr 9

Strony

1823--1837

Opis fizyczny

Bibliogr. 52 poz., rys.

Twórcy

autor

Cortés Corberán V.

autor

Sulikowski B.

Instituto de Catálisis y Petroleoquímica, CSIC, Marie Curie 2, 28049 Madrid, Spain, ncsuliko@cyf-kr.edu.pl

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ5-0022-0140