Mechanism of Hydrogen Abstraction by O- Species in Oxidative Dehydrogenation of Early Al kanes: Propane, Ethane and Methane. Model Theoretical DFT Study

• Autorzy: Góra A. , Broclawik E.
• Języki publikacji: EN

Abstrakty

EN

Decomposition of methanol was adopted as a simple test for standardizing of activity of ZnO containing superbasic catalysts with respect to their applicability in CH3OH synthesis. The values of the rate constants and activation energies were evaluated considering the reaction mechanism. Obtained data were compared with those obtained for Pd/SiO2 and Pt/SiO2 catalysts.

Słowa kluczowe

EN

ODH; alkane activation; hydrogen abstraction; DFT modelling

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2008
• Tom: Vol. 82, nr 9
• Strony: 1793--1799
• Opis fizyczny: Bibliogr. 34 poz., rys.

Twórcy

autor

Góra A.

autor

Broclawik E.

• Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warszawa, Poland,

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