Synthesis and Characterization of Two Novel Mixed-Valent and Metal Oxo-Centered Trinuclear Complexes [Fe2CoO(CHCl2COO)6(py)3] and [Mn2MnO(CHCl2COO)6(py)3]

• Autorzy: Yazdanbakhsh M. , Tavakkoli H.
• Języki publikacji: EN

Abstrakty

EN

Two novel mi3-oxo trinuclear complexes, [Fe2CoO(CHCl2COO)6(py)3] (1) and [Mn2MnO(CHCl2COO)6(py)3] (2) have been synthesized and characterized by IR spectroscopy, elemental analysis, UV-Vis spectroscopy and atomic absorption spectroscopy. Complexes 1 and 2 are mi3-oxo trinuclear compounds with the three metal atoms bridged by six dichloroacetates groups. M3O and MO4 units adopted D3h and D4h local symmetry, respectively, and are surrounded by six bridging dichloroacetates with C2ypsilon local symmetry.

Słowa kluczowe

EN

trinuclear complexes; bridging carboxylate; dichloroacetic acid; IR spectrum; UV-Vis spectrum

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2008
• Tom: Vol. 82, nr 8
• Strony: 1519--1525
• Opis fizyczny: Bibliogr. 18 poz., rys.

Twórcy

autor

Yazdanbakhsh M.

autor

Tavakkoli H.

• Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, Iran,

Bibliografia

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