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Tytuł artykułu

Zeolites as the Modern Catalysts for the High Octane Gasoline Component Production

Identyfikatory
Warianty tytułu
Konferencja
10th Ukrainian-Polish Symposium "Theoretical and Experimental Studies of Interfacial Phenomena and Their Technological Applications", Lviv-Uzlissja, Ukraine
Języki publikacji
EN
Abstrakty
EN
Processes of isobutane with butenes alkylation with the purpose of obtaining the high octane gasoline component (alkylate), being environmentally detrimental due to use of concentrated H2SO4 or HF acids as catalysts, are nevertheless of great industrial importance supplying the world market with approximately 80 mln tons of alkylate yearly. The perspective of zeolite catalysts as the substitutes of the above concentrated acids in the modern alkylation process has been considered. The most effective today’s solid alkylation catalyst of the narrow acid spectrum has been found. Such acidity spectrum is considered to be responsible for the essential prolongation of the effective catalyst lifetime.
Słowa kluczowe
Rocznik
Strony
101--106
Opis fizyczny
Bibliogr. 12 poz., rys.
Twórcy
autor
  • Institute of Bioorganic Chemistry and Petrochemistry, Ukrainian National Academy of Sciences, 50 Kharkivske Chaussee, 02160 Kiev, Ukraine, patrylak@visti.com
Bibliografia
  • l. Weitkamp J. AndTraa Y., Catal. Today, 49,193 (1999).
  • 2. Handbook of Heterogeneous Catalysis, G. Ertl, H. Knozinger, J. Weitkamp (Eds.), Vol. 4, Wiley-VCH, Weinheiml997, p.2039.
  • 3. Nivarthy G.S., Ph. D. Thesis, Twente University, The Netherlands. 1999.
  • 4. Patrylak K.I., Sydorenko Yu.N. And Bortyshevskyi V.A., Alkylation over Zeolites, Scientific Thought,Kiev, 1991 (in Russian).
  • 5. Patrylak K.I. And Taranookha O.M., Preprints: Am. Chem. Soc, 41, 678 (1996) (English translation).
  • 6. Patrylak L. and Bartosh P., Theor. Experim. Chem., 39, 177 (2003) (in Russian).
  • 7. Gregg S.J. and Sing K.S. W., Adsorption, Surface Area and Porosity, 2nd Edn, Academic Press, London (1982).
  • 8. de Boer J.H. and Broekhoff J.C.P., J. Catal., 3, 8 (1967).
  • 9. deBoer J.H. and Broekhoff J.C.P., J. Catal., 10, 153 (1968).
  • 10. Barrett E.P., Joyner L.G. and Halenda P.H., J. Am. Chem. Soc. 73, 373 (1951).
  • 11. Krylov O. V., Catalysis in Industry, 4, 9 (2005) (in Russian).
  • 12. Kashkovskyi V.L, Ph. D. Thesis, Institute of Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Kiev, 1989.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ5-0022-0059
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