Activated Complex in the Decomposition of N2O over Cu

Polič, S.; Senegačnik, M.; Kobal, I.; Zieliński, M.

Artykuł - szczegóły

Tytuł artykułu

Activated Complex in the Decomposition of N2O over Cu

Autorzy

Polič S. , Senegačnik M. , Kobal I. , Zieliński M.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

Decomposition of N2O over Cu wire, at initial N2O pressures 40–60 kPa and temperatures 675–875 K, showed first order kinetics inN2Owith an apparent activation energy of 110 š 16 kJ mol–1. The 15N and 18O kinetic isotope effects under these experimental conditions were determined and interpreted following the Bigeleisen’s formalism. A bent NNO activated complex satisfactorily accounts for the experimental results.

Słowa kluczowe

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2001

Tom

Vol. 75, nr 11

Strony

1729--1738

Opis fizyczny

Bibliogr. 102 poz., rys.

Twórcy

autor

Polič S.

Stefan Institute, POB 3000, 1000 Ljubljana, Slovenia

autor

Senegačnik M.

Stefan Institute, POB 3000, 1000 Ljubljana, Slovenia

autor

Kobal I.

Jagiellonian University, 30-060 Cracow, Poland

autor

Zieliński M.

Jagiellonian University, 30-060 Cracow, Poland

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ5-0018-0058