Evidence for the Formation of Diisocyanodiacetylene in Argon Matrices

• Autorzy: Kołos R.
• Języki publikacji: EN

Abstrakty

EN

Dicyanodiacetylene, NC-CC-CC-CN was dissociated by (i) laser photolysis at 193 nm and (ii) electrical discharges through its mixture with argon. The products, isolated in cryogenic matrices, were analysed by IR spectroscopy. In addition to the bands recently assigned to cyanoisocyanodiacetylene, another group of mutually correlated spectral features has been found. Its carrier is tentatively identified as diisocyanodiacetylene based on ab initio and density functional theory calculations.

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2000
• Tom: Vol. 74, nr 12
• Strony: 1723--1730
• Opis fizyczny: Bibliogr. 16 poz., rys.

Twórcy

autor

Kołos R.

• Institute of Physical Chemistry of the Polish Academy of Sciences, Kasprzaka 44, 01-224 Warsaw, Poland