Generation and Typical Reactions of Thiocarbonyl Ylides

• Autorzy: Mlostoń G. , Heimgartner H.
• Języki publikacji: EN

Abstrakty

EN

In recent years, thiocarbonyl ylides found new application as useful building blocks in syntheses of sulfur containing heterocycles. They were also shown to play an important role as key intermediates in two-step [3+2] cycloaddition reactions. Strategies explored for the generation of thiocarbonyl ylides and their typical reactions including [3+2] cycloadditions,1,3- and 1,5-electrocyclizations, additions of OH, SH, and NH groups, and rearrangements are presented. Reactivities of isolable, push-pull stabilized thiocarbonyl ylides are compared with those proposed as transient species.

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2000
• Tom: Vol. 74, nr 11
• Strony: 1503--1532
• Opis fizyczny: Bibliogr. 133 poz., rys.

Twórcy

autor

Mlostoń G.

autor

Heimgartner H.

• Section of Heteroorganic Compounds, University of Łódź, Narutowicza 68, PL-90-136 Łódź, Poland