The Protonation Equili rium and Decomposition of Amino- and Hydroxyphosphonates, Phos phine Ox ides and Phosphonic Acid

• Autorzy: Doskocz M. , Gancarz R. , Roszak S.
• Języki publikacji: EN

Abstrakty

EN

Protonation states of amino and hydroxyl phosphoroorganic derivatives have been studied. Based on the presented calculations we can state that mono- and di-protonated species on nitrogen are dominating states in solution. The protonation on phosphoryl oxygen occurs only as an effect of dynamic equilibrium between protonated species. The double and tripple protonation lead to very strong acid and thus such states are rather not present even in strong acidic media.

Słowa kluczowe

EN

cleavage of P–C bond; phosphoroorganic compounds; ab initio; protonation

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2007
• Tom: Vol. 81, nr 11
• Strony: 2013--2021
• Opis fizyczny: Bibligr. 41 poz., rys.

Twórcy

autor

Doskocz M.

autor

Gancarz R.

autor

Roszak S.

• Department of Medicinal Chemistry and Microbiology, Faculty of Chemistry, Wroclaw University of Technology, Wyb. Wyspianskiego 27, 50-370 Wroclaw, Poland,

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