The Facile Synthesis, Theoretical Study and Electrochemical Characterization of Poly(Arylene) Derivatives

• Autorzy: Sołoducho J. , Doskocz J. , Nowakowska A. , Cabaj J. , Łapkowski M. , Golba S.
• Języki publikacji: EN

Abstrakty

EN

A convenient and high yield synthetic route to arylene derivatives was reported and their electrochemical character was shown by properties of polymer with alternate arylene and bispyridine, bisthiophene, bisfurane and bisthiazole units. Polmerization is processed as two steps bielectronic oxidation of molecules. In monoelectronic oxidation stableradical cation is formed with spin located on phenothiazine. The electrochemical properties of polymer are dependent on film thick ness deposited on electrode. In the case of the thin layers one can observe characteristic redox couple of phenothiazine oxidation to radical cation. Analysis of polymer behaviour and results of spectrochemical measurements point on mixed type of electroconducting.

Słowa kluczowe

EN

cross-coupling; heterocycles; metalations; Stille reaction; Suzuki coupling; LB films; charge transfer complex; cyclic voltammetry; electropolymerization

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2007
• Tom: Vol. 81, nr 11
• Strony: 2001--2011
• Opis fizyczny: Bibligr. 11 poz., rys.

Twórcy

autor

Sołoducho J.

autor

Doskocz J.

autor

Nowakowska A.

autor

Cabaj J.

autor

Łapkowski M.

autor

Golba S.

• Wrocław University of Technology, Faculty of Chemistry, Department of Medicinal Chemistry and Microbiology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland,

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