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The nano-form of iron catalyst for the carbon nanotubes (CNTs) growth was prepared in a separate process. First, a thin iron layer was thermally deposited under a high vac uum onto the sur face of the SiO2/Si sub strate at about 300 K. That cat a lyst sur face was treated with hydrogen at 700°C, followed by a subsequent heating at 750°C in the pure ethylene at mosphere. After the hydrogen treatment a continuous, smooth Fe layer was turned into a set of well separated Fe nano-pillars. Deposited multi-walled CNTs (MWCNTs) were examined with atomic force (AFM), scanning electron (SEM) and high resolution trans - mission electron (HR-TEM) microscopic techniques. Applied pretreatment of the catalyst with hydrogen and chemical vapour deposition of MWCNTs from pure ethylene al lowed to propose the growth mechanism for long, straight and catalyst free MWCNTs. It seems that this kind of CNTs structure is the most serious candidate in a future nano-electronic. The results suggest a certain control of the diameter of CNTs.
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Tom
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1971--1981
Opis fizyczny
Bibliogr. 49 poz., rys.
Twórcy
autor
autor
- Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland, lstob@ichf.edu.pl
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ5-0017-0031