Aminoalkylphosphines, theWater-Soluble Chiral Phosphines

• Autorzy: Smoleński P. , Pruchnik F. P.
• Języki publikacji: EN

Abstrakty

EN

Chiral water-soluble heterocyclic phosphines 2,2',2''-[1,3,5-diazaphosphinane-1,3,5- triyltris(methyleneimino)]tripropanoic acid (1), 2,2',2''-[1,3,5-diazaphosphinane- 1,3,5-triyltris(methyleneimino)]tris(3-phenylpropanoic) acid (2) and 2,2',2''-[1,3,5-diazaphosphinane- 1,3,5-triyltris(methyleneimino)]tris(4-methylpentanoic) acid (3) were obtained in reactions of tris(hydroxymethyl)phosphine with chiral amino acids: alanine, phenylalanine and leucine. Course of reaction of amino acids depends on the acidity of solution, at pH 6mainly heterocyclic compounds were obtained, however in basic solutions products of Mannich-type condensation 2,2',2''-[phosphinetriyltris(methyleneimino)] tripropanoic acid (4), 2,2',2''-[phosphinetriyltris(methyleneimino)]tris(3-phenylpropanoic) acid (5) and 2,2',2''-[phosphinetriyltris(methyleneimino)]tris(4-methylpentanoic) acid (6) are formed. The prepared compounds were characterized using spectroscopic methods.

Słowa kluczowe

EN

amino acids; aminophosphines; water-soluble phosphines; alanine; phenylalanine; leucine; chiral phosphines

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2007
• Tom: Vol. 81, nr 10
• Strony: 1771--1771
• Opis fizyczny: –1776, Bibliogr. 19 poz., rys.

Twórcy

autor

Smoleński P.

autor

Pruchnik F. P.

• Faculty of Chemistry, University of Wrocław, Joliot-Curie 14, 50-383 Wrocław, Poland,

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