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Stability of Mn(II) Complexes with Acetic Acid Derivatives

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Composition and stability constants of Mn(II) complexes with acetic, glycolic (hydroxyacetic), methoxyacetic and phenylacetic acids, glycine (aminoacetic acid), and sarcosine (N-methylglycine) were determined, at a constant ionic strength = 0.1 KNO3 using the potentiometric method at 20 graduate C. Values of stability constants were found by Bjerrum graphical method and also numerically using Martell and Motekaitis program. The following logK1,graph. values of Mn(II) complexes were found: 2.21 for the complex with acetic acid, 2.45with glycolic acid, 2.10 with methoxyacetic acid, 2.48 with phenylacetic acid, 3.10 with glycine and 3.05 with sarcosine.
Rocznik
Strony
1701--1706
Opis fizyczny
Bibliogr. 16 poz., rys.
Twórcy
autor
autor
  • Institute of Chemistry, University of Silesia, Szkolna 9, 40-006 Katowice, Poland, zcha@us.edu.pl
Bibliografia
  • 1.    Karlson P, Outline of Biochemistry, PWN, Warsaw 1987 (in Polish).
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  • 3.    Traczyk W.Z., Human Physiology in Outline, PZWL, Warsaw 1992 (in Polish).
  • 4. Adam J. and Pribil R., Talanta, 19, 1105 (1972).
  • 5.    John E., Czoik R. and Pedras M., Polish J. Chem., 78, 309 (2004).
  • 6. Holm R.H. and Solomon E.I., Chem. Rev., 96, 2239 (1996).
  • 7.    Hay R.W, Bio - Inorganic Chemistry, PWN, Warsaw 1990 (in Polish).
  • 8. Pettit L.D. and Powell K.J., Stability Constants SC - Database, IUPAC and Academic Software 1993-2000.
  • 9. Murray R.K., Granner D.K., Mayes PA. and Rodwell V.W, Harpefs Biochemistry, ed. 22, Prentice -Hall International Inc., PZWL, Warsaw 1994 (in Polish).
  • 10.   John E., Rev. Roumaine Chim., 39 (2), 171 (1994).
  • 11.   Van Uitert L.G. and Hass C.G., J. Am. Chem. Soc., 75, 451 (1953).
  • 12.   Rossotti F. and Rossotti H., Acta Chem. Scand., 9, 1166 (1955).
  • 13.   Bjerrum J., Metal Amine Formation in Aąueous Solution, P. Hasse and Sohn, Copenhagen 1957.
  • 14.   Martell A.E. and Motekaitis R. J., Determination and Use of Stability Constants, 2nd ed., VCH Publishers Texas A&M University, 1992.
  • 15.   Inczedy J., Analytical Applications of Complex Equilibria, Akademiai Kiado, Budapest 1976.
  • 16.   Bjerrum J., Metal Amine Formation in Aqueous Solution, Copenhagen 1941; Bjerrum J., Chem. Rev.,46,381 (1950).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ5-0017-0002
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