Synthesis, Characterization and Crystal Structure Studies of 1-(4-Chloro-benzenesulfonyl)-piperidin-4-yl-diphenyl-methanol

• Autorzy: Benakaprasad S. , Naveen S. , Anandakumar C. , Sunilkumar Y. , Sridhar M. , Shashidhara Prasad J. , Rangappa K.
• Języki publikacji: EN

Abstrakty

EN

1-(4-Chloro-benzenesulfonyl)-piperidin-4-yl-diphenyl-methanol was synthesized by the condensation of [piperidin-4-yl]-diphenyl-methanol with p-chlorobenzene sulfonylchloride in methylene dichloride as solvent and triethylamine as the base. The compound obtained was characterized by spectroscopic techniques and confirmed by X-ray crystallographic studies. The crystallographic data analysis reveals that the title compound crystallizes in the monoclinic space group P21/c with cell parameters a = 10.214(9capital A, ring, b = 11.371(5)cvapital A, ring, c = 20.939(16)capital A, ring, beta = 115.399(2), V = 2197(3) capital A, ring3 for Z = 4. The structure has been solved by direct methods and refined toR1 = 0.0560 for 3658 observed reflections with I > 2sigma(I). The piperidine ring is in a chair conformation. The geometry around the S atom is distorted from regular tetrahedron.

Słowa kluczowe

EN

sulfonyl chloride; condensation; crystal structure; chair conformation

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2007
• Tom: Vol. 81, nr 5-6
• Strony: 1191--1199
• Opis fizyczny: Bibliogr. 19 poz., rys.

Twórcy

autor

Benakaprasad S.

autor

Naveen S.

autor

Anandakumar C.

autor

Sunilkumar Y.

autor

Sridhar M.

autor

Shashidhara Prasad J.

autor

Rangappa K.

• Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, India,

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