A New Chiral 4-[(E)-2-Ferrocenylvinyl]-1-methylpyridinium Iodide Exhibiting Bulk Second-Order Nonlinear Optical Properties

• Autorzy: Janowska I. , Zakrzewski J. , Palusiak M. , Nakatani K.
• Języki publikacji: EN

Abstrakty

EN

Two new chiral 4-[(E)-2-ferrocenylvinyl]-1-methylpyridinium iodides, having in the 2-position of the ferrocenyl group (R)-1-N,N-dimethylaminoethyl and (S)-2-methoxymethylpyrrolidin- 1-yl substituents were synthesized. The latter compound showed weak second harmonic generation efficiency (0.5 x urea) at 1907 m. The molecular structure and crystal packing of this compound were determined by single-crystal X-ray diffraction and are discussed in relation to its nonlinear optical properties.

Słowa kluczowe

EN

ferrocene; planar chirality; nonlinear optics; second harmonic generation

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2007
• Tom: Vol. 81, nr 5-6
• Strony: 1063--1070
• Opis fizyczny: Bibliogr. 13 poz., rys.

Twórcy

autor

Janowska I.

autor

Zakrzewski J.

autor

Palusiak M.

autor

Nakatani K.

• Department of Organic Chemistry, University of Łódź, 90-136 Łódź, Narutowicza 68, Poland,

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