Synthesis and 1H-NMR Characterization of the Self-Assembly Based on Melamine – 5,5-Diethylbarbituric Acid

• Autorzy: Pokrop A. , Lipkowski P. , Jurczak J.
• Języki publikacji: EN

Abstrakty

EN

The characterization of carbonyl–metal and maleimidato–metal bonding has been performed using the topological analysis of electron distribution function estimated for molecules of ( 5-C5H5)M(CO)3( 1-N-maleimidato) (M = W, Mo) and ( 5-C5H5)Fe(CO)2( 1-N-maleimidato). The Atoms in Molecules (AIM) approach has been applied for characterization of and -components of the metal–ligand bonds. The -electron communication between trans-placed ligands is present in Wand Mo derivatives. The ellipticity parameter is suggested to be a useful and highly sensitive parameter in the analysis of the metal–ligand bonding

Słowa kluczowe

EN

self-assembly; melamine; barbituric acid; hydrogen bonds

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2007
• Tom: Vol. 81, nr 5-6
• Strony: 893--901
• Opis fizyczny: Bibliogr. 16 poz., rys.

Twórcy

autor

Pokrop A.

autor

Lipkowski P.

autor

Jurczak J.

• Department of Chemistry, University of Warsaw, Pasteura 1, 02-093 Warsaw, Poland,

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