Cyclic Voltammetric, Chronoamperometric and Quartz Crystal Microbalance Study on Hydrogen Absorption into and Dissolution of Pd and Pd-noble Metal Alloys

Łukaszewski, M.; Czerwiński, A.

Artykuł - szczegóły

Tytuł artykułu

Cyclic Voltammetric, Chronoamperometric and Quartz Crystal Microbalance Study on Hydrogen Absorption into and Dissolution of Pd and Pd-noble Metal Alloys

Autorzy

Łukaszewski M. , Czerwiński A.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

Hydrogen absorption into and electrochemical dissolution of thin Pd and Pd alloy (Pd–Au, Pd–Rh) layers have been studied in acidic solutions (0.5MH2SO4) with the use of cyclic voltammetry (CV) and chronoamperometry (CA) coupled with the electrochemical quartz crystal microbalance (EQCM). Currents due to hydrogen adsorption and absorption in alfa- and beta-phase are distinguished on CV curves. The amount of absorbed hydrogen depends on electrode potential and increases with the potential decrease. Hydrogen absorbed in Pd–Au and Pd–Rh alloys is oxidized at a lower potential than in the case of pure Pd. In the case of the Pd–Au system the potential region of phase transition is shifted positively in comparison with Pd indicating higher stability of the beta-phase, while for the Pd–Rh system the potential region of phase transition is shifted negatively indicating lower stability of the beta-phase.Hydrogen absorption is accompanied by stresses inside Pd crystal lattice, both phenomena affecting theEQCMresponse.EQCMexperiments indicate that the magnitude and distribution of stresses are different for absorption and desorption processes, which seems to confirm the important role of the stress effect in the phenomenon of absorption/desorption hysteresis. Pd dissolves electrochemically during polarization to sufficiently high potentials in a CV experiment. The amount of dissolved metal increases with an increase in electrode potential and a decrease in scan rate. Due to Pd preferential dissolution during potential cycling of Pd–Au alloys both cyclic voltammogram and frequency-potential response transform towards curves typical of Au electrode.

Słowa kluczowe

palladium palladium alloys hydrogen absorption hysteresis stress electrochemical dissolution electrochemical quartz crystal microbalance

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2007

Tom

Vol. 81, nr 5-6

Strony

847--864

Opis fizyczny

Bibliogr. 100 poz., rys.

Twórcy

autor

Łukaszewski M.

autor

Czerwiński A.

Warsaw University, Department of Chemistry, Pasteura 1, 02-093 Warsaw, Poland, aczerw@chem.uw.edu.pl

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Bibliografia

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