[2+3]-Cycloadditions of Diazoalkanes with Imines of Hexafluoroacetone and Chloral

• Autorzy: Mloston G. , Bodzioch A. , Cebulska Z. , Linden A. , Heimgartner H.
• Języki publikacji: EN

Abstrakty

EN

The reactions of N-arylimines 1 and 2 of hexafluoroacetone and chloral, respectively, with diazoalkanes at –60C to room temperature led to the corresponding 4,5-dihydro- 1H-[1,2,3]triazoles 4 and 5, in a regioselective [2+3]-cycloaddition. The structure of one example in each case has been established by X-ray crystallography. The thermal decomposition of these adducts yielded the corresponding aziridines, bearing two trifluoromethyl and one trichloromethyl group, respectively, at C(2).

Słowa kluczowe

EN

1,3-dipolar cycloaddition; imines; 4,5-dihydro-1H-[1,2,3]triazoles; aziridines; crystal structure

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2007
• Tom: Vol. 81, nr 5-6
• Strony: 631--641
• Opis fizyczny: Bibliogr. 41 poz., rys.

Twórcy

autor

Mloston G.

autor

Bodzioch A.

autor

Cebulska Z.

autor

Linden A.

autor

Heimgartner H.

• Section of Heteroorganic Compounds, University of Lodz, Narutowicza 68, PL-90-136 Lodz, Poland,

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