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It has been shown that photocatalytic activity, surface electroconductivity, and magnetic susceptibility of TiO2 significantly depend on the character and concentration of f-element’s admixture as well as on the temperature and conditions of its thermo-treating. Admixtures of f-elements with variable valence and relatively smaller ionic radius are more effective to reach higher photocatalytic activity, surface electroconductivity, and magnetic susceptibility. Above mentioned parameters of TiO2 increase with addition of a small amount of f-elements as well as after thermo-treating of a sample at 673–873 K in the reducing medium. Photocatalytic activity, electroconductivity, and magnetic susceptibility decrease on the following conditions: increase of an admixture content, thermo-processing in the oxidizing medium or at higher temperature.
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591--598
Opis fizyczny
Bibliogr. 17 poz., rys.
Twórcy
autor
autor
- Chernivtsi National University, Kotsiubinsky St., 2, Chernivtsi, 58012, Ukraine, ikobasa@rambler.ru
Bibliografia
- 1. Kobasa I.M., Polish J. Chem., 78, 553 (2004).
- 2. Mazurkevich Ya.S., ZozulyaN.L, Rotaru V.K., Yurov L.L., Pozhidaeva Z.M., Kobasa I.M. and Blashku A.I., USSR Patent 1688778, Bulletin of Inventions, 40, 58 (1991) (in Russian).
- 3. Kobasa I.M., Functional Mater., 11, 798 (2004).
- 4. Kobasa I.M., Polish J. Chem, 78, 117 (2004).
- 5. Efstathiou A.M., Boudouvas D., Yanwouka N. and Verykios X. E., J. Appl. Catal., l, l (1992).
- 6. Kobasa I.M., Zozulya N.I. and Mazurkevich Ya.S., Theor. and Experimental Chem., 39, 305 (2003) (in Russian).
- 7. Imamura H., Yoshimoshi H. and Harada Y, J. Mol. Catal., 66, 33 (1991).
- 8. ImamuraH.,KonishiT.,Takunage Y,Sakata Y.and TsuchiyaS., Bull. Chem. Soc. Jap., 65,244(l992).
- 9. Tennakone K., Heperuma O.A. and Bandara J.M.S., Sol. Energy Mater., 22, 319 (1991).
- 10. Mazurkevich Ya.S., Homa M.I., Zozulya N.I., Kobasa I.M. and Yatamaniuk Y.M., USSR Patent 1043154, Bulletin of Inventions, 35, 9 (1983) (in Russian).
- 11. Kobasa I.M. and Tarasenko G.P., Theor. and Experimental Chem., 39, 107 (2003) (in Russian).
- 12. Volkenshtein F.F., Surface Physical Chemistry of Semiconductors, Nauka, Moscow 1973, p. 400 (in Russian).
- 13. Tanabe K., Catalysts and Catalytical Processes, Mir, Moscow 1993, p. 172 (in Russian).
- 14. Karakitsou K.E. and Verykios X.E., J. Phys. Chem., 97, 1184 (1993).
- 15. Serebrennikov V. V., Rare-earth Elements and its Compounds in the Electronic Technique, Tomsk State Univ. Publ., Tomsk 1979, p. 144 (in Russian).
- 16. Goroschenko Ya.G., Chemistry of Titanium, Naukova Dumka, Kiev 1970, p. 415 (in Russian).
- 17. Salvador P., Gonzales M.L.C. and Munoz F., J. Phys. Chem., 96, 10349 (1992).
Typ dokumentu
Bibliografia
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bwmeta1.element.baztech-article-BUJ5-0009-0014