Synthesis, Molecular and Crystal Structure of Two Tricyclic N-Aminoimides

Struga, A.; Mirosław, B.; Wawrzycka-Gorczyca, I.; Kossakowski, J.; Kozioł, A.

Artykuł - szczegóły

Tytuł artykułu

Synthesis, Molecular and Crystal Structure of Two Tricyclic N-Aminoimides

Autorzy

Struga A. , Mirosław B. , Wawrzycka-Gorczyca I. , Kossakowski J. , Kozioł A.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

Two new N-aminoimides, 2-amino-4,7-epoxy-3a,4,7,7a-tetrahydro-1H-isoindole- 1,3(2H)dione (I) and 2-amino-8-isopropyl-5-methyl-4,7-ethane-3a,4,7,7a-tetrahydro- 1H-isoindole-1,3(2H)-dione (II), have been synthesized. Both compounds are exo,cis isomers. Crystals of (I) and (II) are noncentrosymmetric with two crystallographically independent molecules (Z’ = 2) in the asymmetric unit. The N-amine groups of the symmetry independent molecules differ in their environment, forming single or bifurcated N–H...O hydrogen bonds. Voluminous hydrocarbon parts evoke orthogonal electrostatic interactions between the imide ring and carbonyl or ether O atoms in (II) and (I), respectively, with C/N...O distances smaller than 3.2 (the shortest being of 2.9 ).

Słowa kluczowe

N-aminoimide crystal structure 1H-isoindole-1,3(2H)-dione derivative orthogonal electrostatic interaction

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2007

Tom

Vol. 81, nr 1

Strony

51--59

Opis fizyczny

Bibliogr. 36 poz., rys.

Twórcy

autor

Struga A.

autor

Mirosław B.

autor

Wawrzycka-Gorczyca I.

autor

Kossakowski J.

autor

Kozioł A.

Department of Medical Chemistry, The Medical University, 02-007 Warszawa, Poland

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Typ dokumentu

Bibliografia

Identyfikator YADDA

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