Synthesis and Characterization of 5,10,15,20-Tetra-(4-decanoyloxyphenyl)porphyrin and Transition Metal Complexes

• Autorzy: Liu W.
• Języki publikacji: EN

Abstrakty

EN

Transition metal complexes of 5,10,15,20-tetra-(4-decanoyloxyphenyl)porphyrin TDPPM [M = Mn, Fe, Co, Ni, Cu, Zn; TDPPH2 = 5,10,15,20-tetra-(4-decanoyloxyphenyl)porphyrin] have been synthesized and characterized by UV-Vis, IR photoacoustic, 1HNMR spectroscopy, elemental analyses, molar conductivity and differential scanning calorimetry (DSC). The ligand and its Zn complex have liquid crystalline behavior. According to the DSC thermogram the Zn complex exhibits a low phase transition temperature at –8.987 graduateC and a wide mesophase range at 175graduateC.

Słowa kluczowe

EN

porphyrin; transition metal complex; synthesis

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2007
• Tom: Vol. 81, nr 1
• Strony: 15--22
• Opis fizyczny: Bibliogr. 14 poz., rys.

Twórcy

autor

Liu W.

• College of Materials Science and Engineering, Shandong University of Technology, Zibo, 255049, P. R. China

Bibliografia

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