Synthesis, Characterization and Electrochemical Property of Dicyclohexyl-18-crown-6 Nickel(II) Bis(dithiolate) Complexes

• Autorzy: Sun Y. , Dong F. , Dou J. , Li D. , Gao X. , Wang D.
• Języki publikacji: EN

Abstrakty

EN

Two organic-inorganic hybrid dicyclohexyl-18-crown-6 nickel(II) bis(dithiolate) complexes, [K(DC18C6-B)]2[Ni(mnt)2] (1) and [K(DC18C6-A)]2[Ni(i-mnt)2] (2) (DC18C6-A = cis-syn-cis-dicyclohexyl-18-crown-6; DC18C6-B = cis-anti-cis-dicyclohexyl- 18-crown-6; mnt = maleonitriledithiolate; i-mnt = isomaleonitriledithiolate), have been synthesized by the reactions of dicyclohexyl-18-crown-6with NiCl2 andK2(mnt) or K2(i-mnt) respectively, and characterized by elemental analysis, FT-IR,UV-Vis spectroscopy and X-ray single crystal diffraction. They both crystallize triclinic, space group P1. Complex 1 shows a neutral molecule composed of two [K(DC18C6-B)]+ complex cations and one [Ni(mnt)2]2– complex anion via two K–N coordination bonds. In complex 2, the [K(DC18C6-A)]+ complex cation and [Ni(i-mnt)2]2– complex anion afford a 1D chain- like structure by N–K–N interactions.

Słowa kluczowe

EN

dicyclohexyl-18-crown-6; nickel bis(dithiolate) complex; synthesis and crystal structure

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2006
• Tom: Vol. 80, nr 12
• Strony: 2001--2009
• Opis fizyczny: Bibliogr. 36 poz., rys.

Twórcy

autor

Sun Y.

autor

Dong F.

autor

Dou J.

autor

Li D.

autor

Gao X.

autor

Wang D.

• Department of Chemistry, Liaocheng University, Liaocheng, 252059, P. R. China

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