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Spin arrangement diagrams for Er2-xRxFe14B (R = Y, Ce) obtained with Mössbauer spectroscopy and phenomenological model

Treść / Zawartość
Identyfikatory
Warianty tytułu
Konferencja
Proceedings of the All-Polish Seminar on Moessbauer Spectroscopy OSSM'2002, June 9-12, 2002, Goniądz, Poland
Języki publikacji
EN
Abstrakty
EN
Two isostructural series of polycrystalline compounds: Er2-xYxFe14B and Er2-xCexFe14B have been studied by 57Fe Mössbauer spectroscopy in the temperature range 80-370 K. The spin reorientation phenomenon (a transition from basal plane to axial easy magnetisation direction) has been studied extensively by a narrow step temperature scanning in the vicinity of the transition. Using the procedure of subtracting the Mössbauer spectra taken for the same compound at different temperatures, it was possible to follow the influence of transition on the shape of spectra. From this procedure it was concluded that in the region of transition each subspectrum splits into two Zeeman sextets, which are characterised by different hyperfine magnetic fields and quadrupole splittings. The consistent way of describing the Mössbauer spectra was proposed. The spin reorientation temperatures have been established for all compositions and compared with the values obtained from theoretical calculations of spin orientation angle based on phenomenological model. The spin arrangement diagrams have been constructed.
Czasopismo
Rocznik
Strony
59--63
Opis fizyczny
Bibliogr. 19 poz., rys.
Twórcy
  • Marian Smoluchowski Institute of Physics, Jagiellonian University, 4 Reymonta, 30-059 Kraków, Poland, Tel.: +48 12/ 632 48 88, Fax: +48 12/ 633 70 86
autor
  • Marian Smoluchowski Institute of Physics, Jagiellonian University, 4 Reymonta, 30-059 Kraków, Poland, Tel.: +48 12/ 632 48 88, Fax: +48 12/ 633 70 86
autor
  • Marian Smoluchowski Institute of Physics, Jagiellonian University, 4 Reymonta, 30-059 Kraków, Poland, Tel.: +48 12/ 632 48 88, Fax: +48 12/ 633 70 86
Bibliografia
  • 1. Andreev AV, Bartashevich MI, Goto T, Zadvorkin SM (1997) Magnetic properties of (Y1−xThx)2Fe14B. J Alloys Compd 262/263:467−470
  • 2. Bogacz BF (2000) On the approximation of the Mössbauer integrals. Molecular Physics Reports 30:15−20
  • 3. Bogacz BF, Rubin J, Pędziwiatr AT, Bartolomé J, Wielgosz R, Artigas M (1999) Calculated and experimental magnetic phase diagrams for (Nd,Y)2(Fe,Ce)14B systems. In: Proc of XXXIV Zakopane School of Physics, Zakopane 1:191−198
  • 4. Burzo E (1998) Permanent magnets based on R-Fe-B and R-Fe-C alloys. Rep Prog Phys 61:1099−1266
  • 5. Buschow KHJ (1988) Permanent magnet materials based on 3d-rich ternary compounds. In: Wohlfarth EP, Buschow KHJ (eds) Ferromagnetic materials, vol. 4. Elsevier, Amsterdam, pp 1−129
  • 6. Buschow KHJ (1991) New developments in hard magnetic materials. Rep Prog Phys 54:1123−1213
  • 7. Coey JMD (1996) Rare-earth iron permanent magnet. Clarendom Press, Oxford
  • 8. Givord G, Li HS, Perrier de la Bathie R (1984) Magnetic properties of Y2Fe14B and Nd2Fe14B single crystals. Solid State Commun 51:857−860
  • 9. Herbst JF, Croat JJ, Pinkerton FE, Yelon WB (1984) Relationships between crystal structure and magnetic properties in Nd2Fe14B. Phys Rev B 29:4176−4178
  • 10. Hirosawa S, Matsuura Y, Yamamoto H, Fujimura S, Sagawa M, Yamauchi H (1985) Magnetization and magnetic anisotropy of R2Fe14B measured on single crystals. J Appl Phys 59:873−879
  • 11. Ibarra MR, Arnold Z, Algarabel PA, Morellon L, Kamarad J (1992) Effect of pressure on the magnetocrystalline anisotropy of (ErxR1−x)2Fe14B intermetallics. J Phys-Condens Matter 4:9721−9734
  • 12. Pędziwiatr AT, Bogacz BF, Gargula R, Wróbel S (2002) Cerium influence on the spin reorientation in Er2−xCexFe14B evidenced by Mössbauer and DSC techniques. J Magn Magn Mater 248:19−25
  • 13. Pędziwiatr AT, Bogacz BF, Gargula R, Wróbel S (2002) Mössbauer and DSC studies of spin reorientations in Er2−xYxFe14B. J Alloys Compd 336:5−10
  • 14. Pędziwiatr AT, Wallace WE (1986) Magnetism of R2Fe14B systems. J Less-Common Metals 126:41−51
  • 15. Piqué C, Burriel R, Bartolomé J (1996) Spin reorientation phase transitions in R2Fe14B (R = Y, Nd, Ho, Er, Tm) investigated by head capacity measurements. J Magn Magn Mater 154:71−82
  • 16. Radwański RJ, Franse JJ (1987) Rare-earth contribution to the magnetocrystalline anisotropy energy in R2Fe14B. Phys Rev B 36:8616−8621
  • 17. Wielgosz R, Pędziwiatr AT, Bogacz BF, Wróbel S (2000) Spin reorientation in Er2Fe14B intermetallic compound. Molecular Physics Reports 30:167−173
  • 18. Wolfers P, Bacmann M, Fruchart D (2001) Single crystal neutron diffraction investigations of the crystal and magnetic structures of R2Fe14B (R = Y, Nd, Ho, Er). J Alloys Compd 317/318:39−43
  • 19. Yamada M, Kato H, Yamamoto H, Nakagawa Y (1988) Crystal-field analysis of the magnetization process in a series of Nd2Fe14B-type compounds. Phys Rev B 38:620−633
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ5-0004-0052
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