Univalent iron monoazaetioporphyrin complexes studied by Mössbauer spectroscopy

• Autorzy: Kaczmarzyk T. , Dziliński K. , Sinyakov G. , Egorova G.
• Konferencja: Proceedings of the All-Polish Seminar on Moessbauer Spectroscopy OSSM'2002, June 9-12, 2002, Goniądz, Poland
• Języki publikacji: EN

Abstrakty

EN

Results of Mössbauer and EPR studies of univalent-iron monoazaetioporphyrin complexes [Fe(I)(MAEP)] are presented in this paper. Fe(I)(MAEP) were generated using the chemical reduction method. Three forms of the univalent-iron monoazaetioporphyrin complexes were observed: (I) typical Fe(I)(MAEP), (II) with an additional electron on the porphyrin ligand [Fe(I)(MAEP•)]- and (III) the Fe(I)(MAEPh) phlorin structure. Electron configuration of Fe(I) ions in these complexes is (dxy)2(dxz ,dyz)4(dz 2)1. The [Fe(I)(MAEP•)]- structure is stable only in solution and it is transferred into Fe(I)(MAEP) in the solid state. Mössbauer parameters for all products of the reduction reaction are given.

Słowa kluczowe

EN

EPR; iron porphyrins; Mössbauer spectroscopy; reduction reactions

• Wydawca: Institute of Nuclear Chemistry and Technology
• Czasopismo: Nukleonika
• Rocznik: 2003
• Tom: Vol. 48,suppl.1
• Strony: 31--34
• Opis fizyczny: Bibliogr. 19 poz., rys.

Twórcy

autor

Kaczmarzyk T.

• Institute of Physics, Technical University of Częstochowa, 19 Armii Krajowej Ave., 42-200 Częstochowa, Poland, Tel./Fax: [phone]

autor

Dziliński K.

• Institute of Physics, Technical University of Częstochowa, 19 Armii Krajowej Ave., 42-200 Częstochowa, Poland, Tel./Fax: [phone]

autor

Sinyakov G.

• Institute of Molecular and Atomic Physics, Belarus Academy of Sciences, 70 F. Skoryny Prosp., 220 072 Minsk, Belarus

autor

Egorova G.

• Institute of Molecular and Atomic Physics, Belarus Academy of Sciences, 70 F. Skoryny Prosp., 220 072 Minsk, Belarus

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