Identyfikatory
Warianty tytułu
Języki publikacji
Abstrakty
A novel material, Apatite II, obtained from a natural source, has been determined to be a good adsorbent for radionuclides of strontium, europium and trivalent actinides, but not caesium, from neutral aqueous solutions containing common chelating agents and inorganic salts at moderate concentrations. This inexpensive, easily available material seems to be a promising backfill for engineered barriers in nuclear waste repositories. However, encapsulation of the sorbent grains loaded with radiostrontium in the Portland cement matrix results in undesirably high leaching rate for this particular radionuclide.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
171--175
Opis fizyczny
Bibliogr. 15 poz., rys.
Twórcy
autor
- Department of Radiochemistry, Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: +48 22/ 811 27 35, Fax: +48 22/ 811 15 32
autor
- Department of Radiochemistry, Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: +48 22/ 811 27 35, Fax: +48 22/ 811 15 32
Bibliografia
- 1. Baes CF Jr, Mesmer RE (1986) The hydrolysis of cations. RE Krieger Publ Co., Malabar
- 2. Bilewicz A, Narbutt J (2001) α-Crystalline polyantimonic acid as an adsorbent for radiostrontium and actinides(III), and as a primary barrier in waste repositories. Radiochim Acta 89:783−784
- 3. Conca J, Strietelmeier E, Lu N, Ware SD, Taylor TP, Kaszuba J, Wright JV (2003) Treatability study of reactive materials to remediate groundwater contaminated with radionuclides, metals and nitrates in a four-component permeable reactive barrier. In: Naftz DL et al. (eds) Handbook of groundwater remediation using permeable reactive barriers. Applications to radionuclides, trace metals, and nutrients. Academic Press, San Diego, pp 221−252
- 4. Conca JL, Wright JV (2000) Treatment of metal-contaminated leachates utilizing fish bones and fish hard parts. U S Patent no. 6,217,775. United States Patent Office, Washington, DC
- 5. Conca J, Wright J, Triay I (2000) PIMS: a simple technology for clean-up of heavy metals and radionuclides throughout the world. In: Baca TE, Florkowski T (eds) The environmental challenges of nuclear disarmament. NATO Science Series, vol. 29. Kluwer, Dordrecht, pp 223−236
- 6. Jeanjean J, Fedoroff M, Faverjon F, Vincent U, Corset J (1996) Influence of pH on the sorption of calcium ions on calcium hydroxyapatite. J Mater Sci 31:6156−6160
- 7. Jedináková-Krizová V (1998) Migration of radionuclides in the environment. J Radioanal Nucl Chem 229:13−18
- 8. Miyake M, Watanabe K, Nagayama Y, Nagasawa H, Suzuki T (1990) Synthetic carbonate apatites as inorganic cation exchangers. Exchange characteristics for toxic ions. J Chem Soc Faraday Trans 86:2303−2306
- 9. Rajec P, Macášek F, Fédor M, Misaelides P, Samajová E (1998) Sorption of caesium and strontium on clinoptiloliteand mordenite-containing sedimentary rocks. J Radioanal Nucl Chem 229:49−55
- 10. Reichert J, Binner JGP (1996) An evaluation of hydroxyapatite-based filters for removal of heavy metal ions from aqueous solutions. J Mater Sci 31:1231−1241
- 11. Smith RM, Martell AE (1976) Critical stability constants. Vol. 4. Plenum Press, New York
- 12. Suzuki T, Hatsushika T, Miyake M (1982) Synthetic hydroxyapatite as inorganic cation exchangers. J Chem Soc Faraday Trans I 78:3605−3611
- 13. Suzuki T, Ishigaki K, Miyake M (1984) Synthetic hydroxyapatite as inorganic cation exchangers. J Chem Soc Faraday Trans I 80:3157−3165
- 14. Wright J, Conca J (2003) PIMS with Apatite II for the remediation of U and Pu (abstract). In: Proc of the Radiochemistry Conf, July 13−16, 2003, Carlsbad, USA, www.radiochemistry.org/2003_conference/abstracts.html
- 15. Xu Y, Schwartz FW, Traina SJ (1994) Sorption of Zn2+ and Cd2+ on hydroxyapatite surfaces. Environ Sci Technol 28:1472−1480
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ5-0004-0032