Electron capture negative ion mass spectra of some freon derivatives

• Autorzy: Asfandiarov N. , Pshenichnyuk S. , Fal’ko V. , Wnorowska J. , Wnorowski K. , Szamrej-Foryś I.
• Konferencja: Proceedings of the Low Energy Electron-Molecule Interactions - 2nd International Symposium, August 29th - September 2nd, 2002, Chlewiska/Siedlce, Poland
• Języki publikacji: EN

Abstrakty

EN

The temperature dependence of dissociative attachment has been investigated in the temperature range 350-575 K for two freon derivatives 1,1,1-C2H3F2Cl and C2F5Cl using Electron Capture Negative Ion Mass Spectra (ECNI MS). The temperature dependence for 1,1,1-C2H3F2Cl is similar to that observed in the case of CF3Cl reported by Illenberger et al. In contrast, C2F5Cl exhibits quite a different spectrum and its temperature behavior. It has been suggested that sigma*C-Cl delocalization onto two empty orbital leads to Cl- ion formation in two different resonance states.

Słowa kluczowe

EN

negative ions; electron capture; freon derivatives

• Wydawca: Institute of Nuclear Chemistry and Technology
• Czasopismo: Nukleonika
• Rocznik: 2003
• Tom: Vol. 48, nr 2
• Strony: 83--88
• Opis fizyczny: Bibliogr. 20 poz., rys.

Twórcy

autor

Asfandiarov N.

• Institute of Physics of Molecules and Crystals, Russian Academy of Science, 151 October Pr., Ufa, 450075 Russia, Tel.: [phone], Fax: [phone]

autor

Pshenichnyuk S.

• Institute of Physics of Molecules and Crystals, Russian Academy of Science, 151 October Pr., Ufa, 450075 Russia, Tel.: [phone], Fax: [phone]

autor

Fal’ko V.

• Institute of Physics of Molecules and Crystals, Russian Academy of Science, 151 October Pr., Ufa, 450075 Russia, Tel.: [phone], Fax: [phone]

autor

Wnorowska J.

• Chemistry Department, University of Podlasie, 3 Maja Str. 54, 08-110 Siedlce, Poland

autor

Wnorowski K.

• Chemistry Department, University of Podlasie, 3 Maja Str. 54, 08-110 Siedlce, Poland

autor

Szamrej-Foryś I.

• Chemistry Department, University of Podlasie, 3 Maja Str. 54, 08-110 Siedlce, Poland

Bibliografia

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