Low energy electrons in non-polar liquids

• Autorzy: Schmidt W. , Illenberger E.
• Konferencja: Proceedings of the Low Energy Electron-Molecule Interactions - 2nd International Symposium, August 29th - September 2nd, 2002, Chlewiska/Siedlce, Poland
• Języki publikacji: EN

Abstrakty

EN

The properties of excess electrons in non-polar liquids have been studied for more than 30 years. Here, pertinent results are reviewed and discussed with respect to the possibility of studying electron-molecule interactions with low energy electrons in the liquid phase. Some new results on the estimate of the electron lifetime in the delocalized state in liquid hydrogen are presented.

Słowa kluczowe

EN

electrons; energetics; kinetics; non-polar liquids; lifetime

• Wydawca: Institute of Nuclear Chemistry and Technology
• Czasopismo: Nukleonika
• Rocznik: 2003
• Tom: Vol. 48, nr 2
• Strony: 75--82
• Opis fizyczny: Bibliogr. 21 poz., rys.

Twórcy

autor

Schmidt W.

• Institut für Chemie-Physikalische und Theoretische Chemie, Freie Universität Berlin, Takustrasse 3, 14195 Berlin, Germany, Tel.: [phone], Fax: [phone]

autor

Illenberger E.

• Institut für Chemie-Physikalische und Theoretische Chemie, Freie Universität Berlin, Takustrasse 3, 14195 Berlin, Germany, Tel.: [phone], Fax: [phone]

Bibliografia

• 1. Bakale G, Sowada U, Schmidt WF (1976) Effect of an electric field on electron attachment to SF6,N2O, and O2 in liquid argon and xenon. J Phys Chem 80:2556−2559
• 2. Balakin AA, Yakovlev BS (1979) Photoionization of trapped electrons in liquid n-hexane. Chem Phys Lett 66:299−302
• 3. Becker KH (2001) Elementary collision processes in plasmas. In: Hippler R, Pfau S, Schmidt M, Schoenbach HK (eds) Low temperature plasma physics. Wiley-VCH, Berlin
• 4. Born M (1920) Volumen und Hydratationswärme der Ionen. Z Physik 1:45−48
• 5. Denzler DN, Hess C, Funk S (2002) Surface femtochemistry: Ultrafast reaction dynamics driven by hot electron mediated reaction pathways. In: Douhal A, Santamaria J (eds) Femtochemistry and femtobiology: Ultrafast dynamics in molecular science. World Scientific, Singapore, pp 652−662
• 6. Döldissen W, Schmidt WF (1979) Saturation of the electron drift velocity in liquid tetramethylsilane. Chem Phys Lett 68:527−528
• 7. Gushchin EM, Kruglov AA, Obodowski I et al. (1982) Electron dynamics in condensed argon and xenon. Sov Phys JETP 55:650−655
• 8. Koizumi H, Katoh R, Lacmann K et al. (1995) Photoconductivity and photoelectron emission of liquid squalane and squalene induced by vacuum-ultraviolet light. Chem Phys Lett 242:320−324
• 9. Koizumi H, Lacmann K, Schmidt WF et al. (1992) Lightinduced electron emission from silicone oils. J Phys D: Appl Phys 25:857−861
• 10. Komeda T, Kim Y, Kawai H (2002) Lateral motion of adsorbate induced by vibrational mode excitation with inelastic tunneling electrons. Surf Sci 502/503:12−17
• 11. Rosenblit M, Jortner J (1995) Dynamics of the formation of an electron bubble in liquid helium. Phys Rev Lett 75:4079−4082
• 12. Sakai Y, Böttcher EH, Schmidt WF et al. (1982) Excess electrons in liquid hydrogen, liquid neon, and liquid helium. J Electrostat 12:89−96
• 13. Sakai Y, Schmidt WF, Khrapek AG (1992) High- and lowmobility electrons in liquid neon. Chem Phys 164:139−152
• 14. Schmidt WF (1979) Excess electron mobility in liquid methane and ethane. In: Int Congress on Radiation Research, Tokyo, pp 202−210
• 15. Schmidt WF (1997) Liquid state electronics of insulating liquids. CRC Press, Boca Raton
• 16. Schmidt WF, Illenberger E, Khrapek AG (2001) Conjecture of the lifetime of delocalized electrons in liquid helium. J Chem Phys 115:10048−10049
• 17. Shibamura E, Takahashi T, Kubota S et al. (1979) Ratio of diffusion coefficient to mobility for electrons in liquid argon. Phys Rev A 20:2547−2557
• 18. Sowada U, Bakale G, Yoshino K et al. (1975) Electron transport in high mobility liquid hydrocarbons and tetramethylsilane. In: 5th Int Conf on Conduction and Breakdown in dielectric Liquids. Delft University Press, Noordwijkerhout, pp 1−4
• 19. Sowada U, Warman JM, de Haas MP et al. (1982) Hotelectron thermalization in solid and liquid argon, krypton and xenon. Phys Rev B: Condens Matter 25:3434−3437
• 20. Weast RC (ed.) (1988) Handbook of chemistry and physics. CRC Press, Boca Raton
• 21. Yoshino K, Sowada U, Schmidt WF (1976) Effect of molecular solutes on the electron drift velocity in liquid Ar, Kr, and Xe. Phys Rev A 14:438−444