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Degradation of polyolefine wastes into liquid fuels

Treść / Zawartość
Identyfikatory
Warianty tytułu
Konferencja
Proceedings of the 2nd Polish-Japanese Workshop on Materials Science "Materials for Sustainable Development in the 21st Century" 12-15 October 2005, Warsaw, Poland
Języki publikacji
EN
Abstrakty
EN
In Poland, the consumption of polymers like polyethylene, polypropylene and polystyrene amounts is nearly one million tons per year. Most of the products made of these polymers becomes wastes in short time. Polymers are very resistant to biodegradation, therefore technologies of their transformation into useful materials should be developed. In our Institute, the technology of catalytic cracking of polyolefines into liquid fuels is studied. Experiments are concentrated on the selection of proper catalyst and on the construction of continuously operated installation for cracking of polyolefine wastes. Experiments on the selection of catalyst were performed in a laboratory scale batch reactor. A big laboratory installation with a yield of ca. 1 kg/h of liquid products was tested with positive results and plans are to construct a pilot plant installation with a yield of 30 kg/h of liquid products. The products of catalytic cracking are separated in a distillation column into gas, gasoline, light oil and heavy oil fractions. The gas is used for heating the reactor. The heavy oil fraction is recycled to the reactor and the gasoline and light oil fractions are the final products. The gasoline fraction can be used as a component of motor gasoline and the light oil fraction can be used as a component of diesel fuel or as a heating oil.
Czasopismo
Rocznik
Strony
89--94
Opis fizyczny
Bibliogr. 9 poz., rys.
Twórcy
autor
autor
  • Department of Nuclear Methods in Process Engineering, Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: +48 22 504 1058, Fax: +48 22 811 15 32, btyminsk@ichtj.waw.pl
Bibliografia
  • 1. Aguado J, Sotelo JL, Serrano DP, Calles A, Escola JM (1997) Catalytic conversion of polyolefines into liquid fuels over MCM-41: comparison with ZSM-5 and amorphous SiO2-Al2O3. Energy Fuels 11:1225−1231
  • 2. Bounaceur R, Warth V, Marquaire PM (2002) Modeling of hydrocarbon pyrolysis at low temperature. Automatic generation of free radical mechanisms. J Anal Appl Pyrolysis 64:103−122
  • 3. Lin YH, Sharratt PN, Garforth AA, Dwyer J (1998)Catalytic conversion of polyolefines to chemicals and fuels over various cracking catalysts. Energy Fuels 12:767−774
  • 4. Sarbak Z (2004) Catalysis in environment protection.Wydawnictwo Naukowe UAM, Poznań (in Polish)
  • 5. Serrano DP, Aguado J, Escola JM (2000) Catalytic cracking of a polyolefine mixture over different acid solid catalysts. Ind Eng Chem Res 39:1177−1184
  • 6. Songip AR, Masuda T, Kuwahara H, Hashimoto K (1994) Production of high-quality gasoline by catalytic cracking over rare-earth metal exchanged Y-type zeolites of heavy oil from waste plastics. Energy Fuels 8:136−140
  • 7. Takuma K, Uemichi Y, Sugioka M, Ayame A (2001)Production of aromatic hydrocarbons by catalytic degradation of polyolefines over H-gallosilicate. Ind Eng Chem Res 40:1076−1082
  • 8. Uemichi Y, Nakamura J, Iloh T, Sugioka M, Gorforth AA, Dwyer J (1999) Conversion of polyethylene into gasoline-range fuels by two-stage catalytic degradation using silica-alumina and HZSM-5 zeolite. Ind Eng Chem Res 38:385−390
  • 9. Walendziewski J (2005) Continuous flow craking of waste plastics. Fuel Process Technol 86:1265−1278
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ5-0003-0032
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