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Properties of novel silicon nitride-based materials

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Konferencja
Proceedings of the 2nd Polish-Japanese Workshop on Materials Science "Materials for Sustainable Development in the 21st Century" 12-15 October 2005, Warsaw, Poland
Języki publikacji
EN
Abstrakty
EN
Our research on the mechanical and thermal properties of magnesium silicon nitride (MgSiN2)-silicon nitride (Si3N4) composite specimens has been reviewed in this paper. The specimen was fabricated by hot-pressing the compressed powder at a temperature between 1550°C and 1700°C for 90 min under a pressure of 75 MPa in a nitrogen atmosphere, using 1 mol% ytterbium oxide (Yb2O3) addition as a sintering aid. Mechanical and thermal properties of MgSiN2 specimen without Si3N4 addition were as follows: Vickers hardness, 18.3 GPa; flexural strength, 371 MPa; fracture toughness, 2.2 MPa m1/2; and thermal conductivity, 22.7 W m-1 K-1. In order to improve these properties, MgSiN2 composite was fabricated with the addition of 0-89 mol% Si3N4. The fracture toughness of MgSiN2 specimen could be enhanced by the addition of Si3N4, e.g., 6.6 MPa m1/2 (4 mol% Si3N4 addition) and 8.7 MPa m1/2 (49 mol% Si3N4 addition). An increase in fracture toughness of MgSiN2-Si3N4 specimen was attributed to the elongation of Si3N4 grains. Moreover, the thermal conductivity of MgSiN2-Si3N4 specimen increased to 32.7 W m-1 K-1 for 29 mol% Si3N4 addition.
Czasopismo
Rocznik
Strony
55--60
Opis fizyczny
Bibliogr. 15 poz., rys.
Twórcy
autor
  • Department of Chemistry, Faculty of Science and Engineering, Sophia University, 7-1 Kioi-cho, Chiyoda-ku, Tokyo 102-8554, Japan, itatani@sophia.ac.jp
Bibliografia
  • 1. Bruls RJ, Hintzen HT, de With G, Metselaar R, van Miltenburg JC (2001) The temperature dependence of the Grüneisen parameters of MgSiN2, AlN and β-Si3N4.J Phys Chem Solids 62:783−792
  • 2. Bruls RJ, Hintzen HT, Metselaar R, van Miltenburg JC(1998) Heat capacity of MgSiN2 between 8 and 800 K.J Phys Chem B 102:7871−7876
  • 3. Groen WA, Kraan MJ, de With G (1993) Preparation,microstructure and properties of MgSiN2 ceramics. J Eur Ceram Soc 12:413−420
  • 4. Hayashi H, Hirao K, Toriyama M, Kanzaki S, Itatani K (2001) MgSiN2 addition as a means of increasing the thermal conductivity of β-Si3N4. J Am Ceram Soc 84:3060−3062
  • 5. Hintzen HT, Swaanen P, Metselaar R, Groen WA, Kraan MJ (1994) Hot-pressing of MgSiN2 ceramics. J Mater Sci Lett 13:1314−1316
  • 6. Inomata Y, Yukino K, Matsunaga T, Wada T (1976) Hot pressing of Si3N4 with magnesium compound additives.Yogyo-Kyokai-Shi 84:534−539
  • 7. Itatani K, Asoo E, Hayashi H, Hirao K, Koda S (2004)Mechanical properties of magnesium silicon nitridesilicon nitride ceramics. Silicate Ind 69:275−280
  • 8. Niihara K (1984) Mechanical properties of chemically vapor deposited nonoxide ceramics. Am Ceram Soc Bull 63:1160−1164
  • 9. Park H, Kim HE, Niihara K (1997) Microstructural evolution and mechanical properties of Si3N4 with Yb2O3 as a sintering additive. J Am Ceram Soc 80:750−756
  • 10. Slack GA (1973) Nonmetallic crystals with high thermal conductivity. J Phys Chem Solids 34:321−335
  • 11. Tanaka S, Itatani K, Hintzen HT, Delsing ACA, Okada (2004) Effect of silicon nitride addition on the thermal and mechanical properties of magnesium silicon nitride.J Eur Ceram Soc 24:2163−2168
  • 12. Tanaka S, Itatani K, Uchida H et al. (2002) The effect of rare-earth oxide addition on the hot-pressing of magnesium-silicon nitride. J Eur Ceram Soc 22:777−783
  • 13.TIC (2002) Silicon carbide, silicon nitride and fiber reinforcement of ceramics. TIC, Tokyo (in Japanese)
  • 14.Uchida H, Itatani K, Aizawa M, Howell FS, Kishioka A (1997) Synthesis of magnesium silicon nitride by the nitridation of powders in the magnesium-silicon system.J Ceram Soc Japan 105:934−939
  • 15.Uchida H, Itatani K, Aizawa M, Howell FS, Kishioka A(1999) Preparation of magnesium silicon nitride powder by the carbothermal reduction technique. Adv Powder Technol 10:133−143
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ5-0003-0026
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