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Abstrakty
A series of compounds with formulas [Ni(CO)2R4P2S2] and [Ni2(Co)6-mi-R4P2S2] (R = Me, Et, Prn, Bun and Ph) have been prepared photochemically by the reaction of Ni(CO)4 with R2PSPSR2 using a 400 Wmedium pressure mercury lamp through a quartz-walled immersion well reactor. They were characterized by elemental analyses, IR and 31PNMR spectroscopy. The results reveal, that the disphosphine disulfide ligands show disubstitution and, thus, act as a bidentate species or monosubstitution and so act as a bridging ligand.
Słowa kluczowe
Wydawca
Czasopismo
Rocznik
Tom
Strony
983--987
Opis fizyczny
Bibliogr. 31 poz., rys.
Twórcy
autor
autor
- Department of Chemistry, Faculty of Science, Hebron University, P.O. Box 40, Hebron, West bank, Palestine
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ4-0002-0014