Displacement of CO from Ni(CO)4 by Diphosphine Disulfide Derivatives via a Photochemical Reaction

Aqra, F.; Jamhour, R.

Artykuł - szczegóły

Tytuł artykułu

Displacement of CO from Ni(CO)4 by Diphosphine Disulfide Derivatives via a Photochemical Reaction

Autorzy

Aqra F. , Jamhour R.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

A series of compounds with formulas [Ni(CO)2R4P2S2] and [Ni2(Co)6-mi-R4P2S2] (R = Me, Et, Prn, Bun and Ph) have been prepared photochemically by the reaction of Ni(CO)4 with R2PSPSR2 using a 400 Wmedium pressure mercury lamp through a quartz-walled immersion well reactor. They were characterized by elemental analyses, IR and 31PNMR spectroscopy. The results reveal, that the disphosphine disulfide ligands show disubstitution and, thus, act as a bidentate species or monosubstitution and so act as a bridging ligand.

Słowa kluczowe

reaction mechanism metal carbonyl

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2006

Tom

Vol. 80, nr 6

Strony

983--987

Opis fizyczny

Bibliogr. 31 poz., rys.

Twórcy

autor

Aqra F.

autor

Jamhour R.

Department of Chemistry, Faculty of Science, Hebron University, P.O. Box 40, Hebron, West bank, Palestine

Bibliografia

1. Corradini R, J. Chem. Phys., 31, 1676 (1959).
2. Wei C.H., Inorg. Chem., 8, 2384 (1969).
3. Darensbourg D.J. and Incorvia M.J., J. Organometal. Chem., 171, 89 (1979).
4. Darensbourg D.J. and Zalewski D.J., Inorg. Chem., 23, 4382 (1984).
5. Kiviaaho J., Niemelae M.K., Reinikanen M., Yaara T., Pakkanen T.A. and Elsvier J., J. Mol. Catal. A: Chem., 121, l (1997).
6. Gao Y.C., Lin Y., Liu X., Wang Y.Y. and Shi Q.Z., Trans. Met. Chem., 28, 149 (2003).
7. Asali K.J. and Al Janaydeh H., Trans. Met. Chem., 28, 193 (2003).
8. Almond M.J., Sarikahya F. and Senturk O.S., Polyhedron, 16, 1101 (1997).
9. Sarikahya F. and Senturk O.S., Synth. React. Inorg. Met.-Org. Chem., 31, 1843 (2001).
10. Cowley A.H., Chem. Rev., 65(6), 617 (1965).
11. Cotton F.A., Franz B.A., Hunter D.L. and Mester Z.C., Inorg. Chim. Acta, 11,111 (1974).
12. WagnerK.R,HessR.W.,TreichelRM.andCalabreseJ.C.,Inorg. Chem., 14, 1121 (1975).
13. Shriver D. and Drezdzon M., Manipulation of'Air Sens itive Compounds, 2nd edit., Wiley Interscience,Toronto, 1986.
14. Moeller T, Birch H.J. and Nielson N.C., Inorg. Synth., 4, 71 (1953).
15. Christen P.J., Van der Linde L.M. and Hooge F.N., Rec. Trav. Chim., 78, 161 (1959).
16. Nierbergall H. and Langenfeld B., Chem. Ber., 95, 64 (1962).
17. Butter S.A. and Chatt J., Inorg. Synth., 15, 186 (1974).
18 Vogel A.I., Text-Book of Practical Organic Chemistry, 3rd edit., Longman, London, (1977).
19. Cotton F.A. and Wilkinson G.,AdvancedInorganic Chemistry, 5th edit., Wiley Intescience, NY, (1988).
20. Cowely A.H. and White W.D., Spectrochim. Acta, 22, 1431 (1966).
21. McQuillan G.P. and Oxton I.A., J. Chem. Soc. Dalton Trans., 895 (1979).
22. Teichmann H., Angew. Chem. Int. Ed. Engl., 4, 785 (1965).
23. Wang J., Shen J., Gao Y, Shi Q. and Basalo F., Coord. J. Chem., 23, 345 (1991).
24. Labroue D. and Poilblane R., Inorg. Chim. Acta, 6, 387 (1972).
25. Sisak A., Sisak C., Ungvary F., Palyi G. and Marko L., J. Organometal. Chem., 90, 77 (1975).
26. Meek D.W. and Nicpoń R, J. Am. Chem. Soc., 87, 4951 (1965).
27. Claver C., Ruiz A., Masdeu M.A., Yinas J., Saballs T., Lahoz F.J. and Plou F.J., J. Organometal. Chem.,373,269(1989).
28. Grevels F.W, Angew Chem. Int. Ed. Engl., 26, 885 (1987).
29. Grevels F.W., Jacke J. and Seevogel K., J. Mol. Struct., 174, 107 (1988).
30. Turner J.J., J. Am. Chem. Soc., 113, 8437 (1991).
31. Strauss H.L., J. Am. Chem. Soc., 114, 905 (1992).

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ4-0002-0014