Investigation of the Y2X3-Cu2X-SnX2 (X = S, Se) Systems

• Autorzy: Shemet V. , Gulay L. , Stępień-Damm J. , Pietraszko A. , Olekseyuk L.
• Języki publikacji: EN

Abstrakty

EN

The interactions between the components in theY2X3-Cu2X-SnX2 (X = S, Se) systems at 870 K were determined using X-ray powder diffraction. The existence of the compound YCuS2 and the Y(2+x)/3Cu2-xS2 (0 x 0.52) solid solution was confirmed in the Y2S3-Cu2S section. The existence of the solid solution Y(2+x)/3Cu2-xSe2 (0 x 1) was confirmed in the Y2Se3-Cu2Se section. No compounds were found in the Y2S3-SnS2 and Y2Se3-SnSe2 sections. The formation of the compounds Cu4SnS4, Cu2SnS3, Cu4Sn7S16 in the Cu2S-SnS2 system and the Cu2SnSe3 compound in the Cu2Se-SnSe2 system was confirmed. The formation of the Y3Cu1-4xSn1+xS7 (0 x 0.09) solid solution and the Y2Cu0.20Sn0.95S5 compound was determined in the Y2S3-Cu2S-SnS2 system. The existence of the compound Y3CuSnSe7 in the Y2Se3-Cu2Se-SnSe2 system was confirmed.

Słowa kluczowe

EN

X-ray analysis; isothermal section; crystal structure; phase diagram

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2006
• Tom: Vol. 80, nr 6
• Strony: 943--955
• Opis fizyczny: Bibliogr. 29 poz., rys.

Twórcy

autor

Shemet V.

autor

Gulay L.

autor

Stępień-Damm J.

autor

Pietraszko A.

autor

Olekseyuk L.

• Department of General and Inorganic Chemistry, Volyn State University, Voli Ave 13, 43009 Lutsk, Ukraine

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