Tytuł artykułu
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Abstrakty
Two new steroids dehydroadynerizoside (1) and neristigmol (2) have been isolated from the fresh, uncrushed leaves of Nerium oleander and their structures elucidated as 3beta-O-(beta-D-2-deoxy-rhamnosyl)-8,14beta-epoxy-5beta-carda-16,20(22)-dienolide and hexyl p-stigmasteryloxy-benzoate, respectively. The structure elucidation is based on spectroscopic methods including 1D NMR (1H NMR, 13C NMR) and 2D NMR (1H-1H COSY, NOESY, HMQC, HMBC and J-resolved) and chemical transformation.
Słowa kluczowe
Wydawca
Czasopismo
Rocznik
Tom
Strony
445--452
Opis fizyczny
Bibliogr. 20 poz.
Twórcy
autor
autor
autor
autor
autor
- International Center for Chemical Sciences, H.E.J. Research Institute of Chemistry, University of Karachi, Karachi - 75270, Pakistan
Bibliografia
- 1. Chopra R.N., Nayar S.L. and Chopra I.C., Glossary of Indian Medicinal Plants, Council of Scientific and Industrial Research, New Delhi, 1956, p. 175.
- 2. Dymock W., Warden C.J.H. and Hooper D., Pharmacographia Indica, Vol. 2. The Institute of Health and Tibbi Research. Republished under the auspices of Hamdard National Foundation of Pakistan, 1891, p. 398.
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- 5. Wang S. Li, Chen H., Yang H. and Wang W.Y., CA: 132, 262660e, (2000).
- 6. Begum S., Sułtana R. and Siddiąui B.S., Phytochemistry, 44, 329 (1997).
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- 8. Siddiqui S., Hafeez F. and Siddiqui B.S., J. Nat. Prod., 49, 1086 (1986).
- 9. Siddiqui S., Hafeez F., Begum S. and Siddiąui B.S., Phytochemistry, 26, 237 (1987).
- 10. Begum S., Siddiqui B.S., Sułtana R., Zia A. and Suria A., Phytochemistry, 50, 435 (1999).
- 11. Bhacca N.S. and Williams D.H., Applications of NMR Spectroscopy in Organic Chemistry, Holden-Day, Inc., San Francisco, London, Amsterdam, 1966, p. 81.
- 12. Fieser L.F. and Fieser M., Steroid, Chapman and Hall: London, 1959, pp. 734-735.
- 13. Seo S., Tomita Y. and Tori K., Tetrahedron Lett., 1, 7 (1975).
- 14. Siddiqui B.S., Sultana R., Begum S., Zia A. and Suria A., J. Nat. Prod., 60, 540 (1997).
- 15. Breitmier E., Hass G. and Voelter W., Atlas of Carbon-13 NMR Data, Vol. 2, Compound No. 1967 (1968).
- 16. Kobaisy M., Abramowski Z., Lermer L., Saxena G., Hancocks R.E.W. and Towers G.H.N., J. Nat. Prod.,60, 1210(1997).
- 17. Abe F. and Yamauchi T., Phytochemistry, 31, 2459 (1992).
- 18. Alam M.S., Chopra N., Ali M. and Niwa M., Phytochemistry, 41, 1197 (1996).
- 19. Shaia M.A., Shameel S., Ahmad V. and Usmanghani K., Pakistan J. Sci. Ind. Res„ 40, 20 (1997).
- 20. Yamaguchi K., Spectral Data ofNatural Products; Elsevier, Amsterdam, Vol. l, 1970,pp. 135,142-144.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ3-0006-0042