Dicyclopentadienylaluminium Chiral Alkoxides

• Autorzy: Kunicki A. , Cebulski A. , Leszczyńska K. , Kowalczyk K. , Zachara J.
• Języki publikacji: EN

Abstrakty

EN

The reactions of Cp3Al with rac-1-phenyl-1-propanol, rac-2-phenyl-1-propanol and rac-1-phenyl-2-propanol lead to the formation of dicyclopentadienylalkoxy bridged dimers containing chiral alkoxy groups; (R,S) and (R*,R*) diastereoisomerswere found in the reaction mixture. The 1H and 13C NMR study showed a differentiation of signal patterns for diastereoisomers depending on the symmetry of a compound and of an anisotropic character of the chiral ligand.

Słowa kluczowe

EN

aluminum; cyclopentadienyl; alkoxide

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2006
• Tom: Vol. 80, nr 3
• Strony: 439--444
• Opis fizyczny: Bibliogr. 26 poz.

Twórcy

autor

Kunicki A.

autor

Cebulski A.

autor

Leszczyńska K.

autor

Kowalczyk K.

autor

Zachara J.

• Warsaw University of Technology, Faculty of Chemistry, Koszykowa 75, 00-662 Warsaw, Poland

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