Synthesis, Characterization and Crystal Structures of Diorganotin(IV) Complexes with 2-Mercapto-4-methyl-5-thiazoleacetic Acid

• Autorzy: Zhang R. , Sun F. , Ma C. , Zhang J.
• Języki publikacji: EN

Abstrakty

EN

The organotin(IV) complexes, [(C4H4NS2CH2CO2)R2Sn(OMe)OSnR2]2 (R =Me1, n-Bu 2, Ph 3, PhCH2 4), have been synthesized and characterized by IR and 1H NMR spectroscopy. The structures of 1 and 2 have also been determined by X-ray crystallography. The structure analyses show that both complexes 1 and 2 feature a centrosymmetric core arranged as a ladder. Links between pairs of tin atoms are afforded by mi2-methoxo groups and each carboxylate anion coordinates an exocyclic tin atom exclusively, in the monodentatemode.Moreover, the packing of complexes 1 and2 are stabilized by the hydrogen bonding interactions.

Słowa kluczowe

EN

diorganotin; 2-mercapto-4-methyl-5-thiazoleacetic acid; crystal structure

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2006
• Tom: Vol. 80, nr 3
• Strony: 367--376
• Opis fizyczny: Bibliogr. 23 poz.

Twórcy

autor

Zhang R.

autor

Sun F.

autor

Ma C.

autor

Zhang J.

• Department of Chemistry, Liaocheng University, Liaocheng 252059, P. R. China

Bibliografia

• l. Davies A.G. and Smith P.J., in Comprehensive Organometallic Chemistry, 2, Wilkinson G., Stone F.G.A., Abel E.W. (Eds.), Pergamon Press, Oxford, 1982.
• 2. Blunden S.J. and Chapman A., in Organotin Compounds in the Environment, Organometallic Compounds in the Environment, Craig, P.J. (Ed.), Longman, Harlow, 1986.
• 3. Molloy K.C., Purcell T.G., Hahn E., Schumann H. and Zuckerman J. J., Organometallics, 5,85 (l 986).
• 4. Molloy K.C., Quill K. and Noweli I.W., J. Chem. Soc, Dalton Trans., 101 (1987).
• 5. GielenM.,Appl. Organomet. Chem., 16,481 (2002).
• 6  Zubita J.A. and Zuckerman J.J., Inorg. Chem., 24, 251 (1987).
• 7. Sandhu G.K., Gupta R., Sandhu S.S. and Parish R.V., Polyhedron, 4, 81 (1985).
• 8. Sandhu G.K.,Gupta R.,Sandhu S.S.,Parish R.V.and Brown K.,J. Organomet. Chem., 279,373 (1985).
• 9. Lochhart T.P. and Davidson F., Organometallics, 6, 2471 (1987).
• 10. Nowell I.W., Brooks J.S., Beech G. and Hill R., J. Organomet. Chem., 244, 119 (1983).
• 11. Parulekar C.S., Jain V.K., Das T.K., Gupta A.R., Hoskins B.F. and Tiekink E.R.T., J. Organomet. Chem.,372, 193 (1989).
• 12. Narula S.P., Bharadwaj S.K., Sharma H.K., Mairesse G., Barbier P. and Nowogrocki G., J. Chem. Soc., Dalton Trans., 1719(1988).
• 13. Ng S.W., Wei C. and Kumar Das V.G., J. Organomet. Chem., 412, 39 (1991).
• 14. Teoh S.G., Looi E.S., Teo S.B. and Ng S.W., J. Organomet. Chem., 509, 57 (1996).
• 15. Davies A.G., in Comprehensive Organometallic Chemistry II, Abel E.W., Stone F.G.A., Wilkinson G. (Eds.), Pergamon, England, 1995.
• 16. TiekinkE.R.T.,Appl. Organomet. Chem., 5, l (1991).
• 17. TiekinkE.R.T., Trends in Organomet. Chem., 1, 71 (1994).
• 18. Ma C.L. and Sun J.F., Dalton Trans., 1785 (2004).
• 19. Ma C.L., Han Y.F., Zhang R.F. and Wang D.Q., Dalton Trans., 1832 (2004).
• 20. Ma C.L., Han Y.F. and Zhang R.F., J. Organomet. Chem., 689, 1675 (2004).
• 21. Sisido K., Takeda Y. and Kinugawa Z., J. Am. Chem. Soc., 83, 538 (1961).
• 22. Chandra K., Sharma R.K., Garg B.S. and Singh R.P., J. Inorg. Nucl. Chem., 42, 187 (1980).
• 23. Cox M.J., Mohamed-Ibrahim M.I. and Tiekink E.R.T., Main Group Met. Chem., 20, 207 (1997).