Conductivity of 1-Butyl-3-methyl-imidazolium Chloride Solutions in Alcohols

Domańska, U.; Bogel-Łukasik, E.

Artykuł - szczegóły

Tytuł artykułu

Conductivity of 1-Butyl-3-methyl-imidazolium Chloride Solutions in Alcohols

Autorzy

Domańska U. , Bogel-Łukasik E.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

This work presents the ionic conductivity of 1-butyl-3-methylimidazolium chloride [bmim][Cl]'s solutions in alcohols (ethanol, 1-butanol, 1-hexanol, 1-octanol, 1-decanol, 2-butanol, 2-methyl-2-propanol) and that of pure alcohols measured in wide range of temperature and concentration. The values of limiting conductance were determined by the Onsager limiting law. The molar conductivities of these systems were presented as a function of temperature and concentration. The mathematical description of ionic conductivities data by the Vogel-Tammen-Fulcher equation was made. It was shown that the conductivity of [bmim][Cl]'s solutions in the relatively low dielectric constant media is affected by the length of an alcohol carbon chain.

Słowa kluczowe

[bmim]Cl ionic conductivity Onsager limiting law Vogel-Tammen-Fulcher equation

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2006

Tom

Vol. 80, nr 1

Strony

189--203

Opis fizyczny

Bibliogr. 22 poz.

Twórcy

autor

Domańska U.

autor

Bogel-Łukasik E.

Physical Chemistry Division, Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland

Bibliografia

1. Bonhóte R, Dias A.-R, Papageorgiou N., Kalyanasundaram K. and Gratzel M., Inorg. Chem., 35, 1168 (1996).
2. Avent A.G., ChalonerP.A., Day M.R, Seddon K.R. and We lton T., J. Chem. Soc. Dalton Trans., 23,3405 (1994).
3. Hirao M., Ito K. and Ohno H., Electrochim. Acta, 45, 1291 (2000).
4. Yoshio M., Mukai T., Kanie K., Yoshizawa M., Ohno H. and Kato T., Chem. Lett., 31, 320 (2002).
5. Watanabe W. and Mizumura T., Solid State Ionics, 86-88, 353 (1996).
6. Noda A. and Watanabe W., Electrochim. Acta, 45, 1265 (2000).
7. McEwen A.B., Ngo H.L., LeCompte K. and Goldman J.L., J. Electrochem. Soc., 146, 1687 (1999).
8. Welton T., Chem. Rev., 99, 2071 (1999).
9. Wasserscheid R and Keim W., Angew. Chem. Int. Ed., 39, 3772 (2000).
10. Ogihara W, Sun J., Forsyth M., McFarlane D.R., Yoshizawa M. and Ohno H., Electrochim. Acta, 49,1797(2004).
11. Susan A.B.H., Noda A., Mitsusushima S. and Watanabe M., Chem Commun., 938 (2003).
12. Lu W., Fadeev A.G., Qi B. and Mattes B.R., J. Electrochem. Soc., 151, H33 (2004).
13. Domańska U., Bogel-Łukasik E. and Bogel-Łukasik R., J. Phys. Chem. B, 107, 1858 (2003).
14. Domańska U. and Bogel-Łukasik E., Ind. Eng. Chem. Res., 42, 6986 (2003).
15. Domańska U., Bogel-Łukasik E. and Bogel-Łukasik R., Chem. Eur. J., 9, 3033 (2003).
16. Domańska U. and Bogel-Łukasik E., Fluid Phase Equilib., 218, 123 (2004).
17. Domańska U. and Bogel-Łukasik E., Green Chem., 6, 299 (2004).
18. Najdanovic-Visak V., Esperanca J.M.S.S., Rebelo L.P.N., Nunes da Ponte M., Guedes H.J.R.,Seddon K.R. and Szydłowski J., Phys. Chem. Chem. Phys., 4, 1701 (2002).
19. Xu H., Zhao R, Xu D., Liu F. and Gao G., J. Chem. Eng. Data, 50(1), 133 (2005).
20. Abbot A.R and Schifrrin D.J., J. Chem. Soc. Faraday Trans., 86, 1453 (1990).
21. Salomon M. and Uchiyama M.C., J. Solution Chem., 16, 21 (1987).
22. Hagiwara R., Hirashige T., Tsuda T. and Ito Y, J. Electrochem. Soc., 149(1), Dl (2002).

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ3-0006-0017