A New Approach to Synthesis of Questiomycin A: Oxidative Cyclocondensation of ortho-Aminophenol

• Autorzy: Giurg M. , Wiech E. , Piekielska K. , Gębala M. , Młochowski J. , Wolański M. , Ditkowski B. , Peczyńska-Czoch W.
• Języki publikacji: EN

Abstrakty

EN

Oxidation of ortho-aminophenol (1) to 2-amino-3H-phenoxazin-3-one (2) by air,manganese( IV) oxide, hydrogen peroxide or tert-butylhydroperoxide in the presence of different activators including such enzymes as laccase and peroxidase was studied. The most effective oxidants were air/Co(salen), MnO2/2,6-dicarboxypyridine complex 3k, H2O2/ebselen, H2O2/2,2'-dicarbamoylphenyldiphenyl disenide and TBHP/diphenyl diselenides 4d and 4e. Laccase and peroxidase were less active agents. The six-electron cyclocondensation mechanism is discussed.

Słowa kluczowe

EN

catalysis; ebselen; laccase; oxidation; peroxidase; questiomycin

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2006
• Tom: Vol. 80, nr 2
• Strony: 297--306
• Opis fizyczny: Bibliogr. 36 poz.

Twórcy

autor

Giurg M.

autor

Wiech E.

autor

Piekielska K.

autor

Gębala M.

autor

Młochowski J.

autor

Wolański M.

autor

Ditkowski B.

autor

Peczyńska-Czoch W.

• Department of Organic Chemistry, Faculty of Chemistry, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

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