The Generalized NRTL Model Associated with the Peng-Robinson Equation of State to Predict Liquid-Liquid Equilibria Between Hydrocarbons,Water and Ethylene Glycol

• Autorzy: Neau E. , Nicolas C. , Jaubert J. , Mutelet F.
• Języki publikacji: EN

Abstrakty

EN

In this study, the generalized NRTLmodel is combined with the Peng-Robinson equation of state in order to predict the liquid-liquid equilibrium of binary systems containing hydrocarbons, water and glycols. In the proposed model, the binary interaction parameters of theNRTLmodel are predicted bymeans of a group contributionmethod, while the volume and surface-area parameters of pure components introduced in the generalized NRTL version are estimated from the UNIFAC group contribution method. The results obtained in this paper are comparedwith those provided bywell knownmodels described in the literature.

Słowa kluczowe

EN

liquid-liquid equilibria; equation of state; gE model; water + hydrocarbon systems

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2006
• Tom: Vol. 80, nr 1
• Strony: 27--35
• Opis fizyczny: Bibliogr. 42 poz., rys.

Twórcy

autor

Neau E.

autor

Nicolas C.

autor

Jaubert J.

autor

Mutelet F.

• Laboratoire MSNM-GP, UMR 6181, Faculté des Sciences de Luminy, Université de la Méditerranée, 13288 Marseille, Cedex 9, France

Bibliografia

• 1. Trassy L., Doctoral Thesis, Universite d'Aix-Marseille II, 1998.
• 2. Fredenslund A., Gmehling J. and Rasmussen P, "Vapor-Liquid Equilibria Using UNIFAC, Agro Contribution Method", Elsevier, Amsterdam, 1977.
• 3. Panagiotopoulos A.Z. and Reid R.C., ACS Division of Fuel Chemistry, 30, 46 (1985).
• 4. Kontogeorgis G.M., Voustas E., Vakoumis I. and Tassios D.P., Ind. Eng. Chem. Res., 35,4310 (1996).
• 5. Derawi S., Michelsen M., Kontogeorgis G.M. and Stenby E., Fluid Phase Equilib., 209, 163 (2003)
• 6. Robinson D.B. and Peng D.Y., Gas Processor Association, Research Report RR-28 (1978).
• 7 Soave G., Chem. Eng. Sci., 27, 1197 (1972).
• 8. Bondi A., J. Phys. Chem., 68, 441 (1964).
• 9. Crampon C., Trassy L., Avaullee L., Neau E. and Coniglio L., Fluid Phase Equilib., 216, 95 (2004)
• 10. Coniglio L., Doctoral Thesis, Universite d'Aix-Marseille II, 1993.
• 11. Renon H. and Prausnitz J.M., AIChE Journal, 14, 135 (1968).
• 12 Marina J.M. and Tassios D., Ind. Eng. Chem. Process. Des. Dev., 12, 271 (1973).
• 13. Fuehner H., Ber. Dtsch. Chem. Ges., 57, 510 (1924).
• 14. Polak J. and Lu B.C.-Y., Can. J. Chem., 51, 4018 (1973).
• 15 Black C., Joris G.G. and Taylor H.S., J. Chem. Phys., 16, 537 (1948).
• 16. Nelson H.D. and De Ligny C.L., Rec. Trav. Chim. Pays-Bas, 87, 528 (1968).
• 17. Jonsson J.A., Vejrosta J. and Novak J., Fluid Phase Equilib., 9, 279 (1982).
• 18. Englin B.A., Plate A.F., Tugolukov V.M. and Pryanishnikov M.A., Khim. Tekhnoi. Topi. Masel, 10, (1965).
• 19. Pierotti R.A. and Liabastre A.A., U.S. NITS PB Rep., 21163 (1972).
• 20. Price L.C., Am. Assoc. Pet. Geol. Buli, 60, 213 (1976).
• 21. Groschuff E.Z., Elektrochem., 17, 348 (1911).
• 22. Pavia R.A., Doctoral Thesis, North Carolina State College, Raleigh, N.C., U.S.A.
• 23. Brown R.L. and Wąsik S.P., J. Res. Natl. Bur. Stand., Sect. A, 78, 453 (1974).
• 24. Schwarz F.P., Anal. Chem., 52, 10 (1980).
• 25. Sanemasa L, Araki M., Deguchi T. and Nagai H., Chem. Lett., 2, 225 (1981).
• 26. Staveley L.A.K., Jeffes J.H.E. and Moy J.A.E., Trans. Faraday Soc., 39, 5 (1943).
• 27. Arnold D.S., Plank C.A., Erickson E.E. and Pikę F.P., Ind. Eng. Chem., 3, 253 (1958).
• 28. Alexander D.W., J. Phys. Chem., 63, 1021 (1959).
• 29. Franks F., Gent M. and Johnson H.H., J. Chem. Soc., 2716 (1963).
• 30. Goldman S., Can. J. Chem., 52, 1668 (1974).
• 31. Sanemasa I., Araki M., Deguchi T. and Nagai H., Bull. Chem. Soc. Jpn., 55, 1054 (1982).
• 32. Moule D.C. and Thurston W., Can. J. Chem., 44, 1361 (1966).
• 33. Karlsson R.J., Chem. Eng. Data, 18(3), 290 (1973).
• 34. Glasoe P.K. and Schultz S.D., J. Chem. Eng. Data, 17, 66 (1972).
• 35. Rosenbaum C.K. and Walton J.H., J. Am. Chem. Soc., 52, 3568 (1930).
• 36. Brown R.L. and Wąsik S.P., J. Res. Natl. Bur. Stand., Sect. A, 78, 453 (1974).
• 37. Bradley R.S., Dew M.J. and Munro D.C., High Temp.-High Pressures, 5, 169 (1973).
• 38. Chernoglazova F.S. and Simulin Yu.N., Zh. Fiz. Khim., 50, 809 (1976).
• 39. Derawi S.O., Kontogeorgis G.M., Stenby E.H., Haugum T. and Fredheim A.O.,J. Chem. Eng. Data, 47,169(2002).
• 40. Staveley L.A.K. and Milward G.L., J.Chem.Soc., 4369 (1957).
• 41. Kugo M., Fujikawa M. and Tamahori T., Mem. Fac. Eng. Hokkaido Univ.,II, 41 (1960).
• 42. Mandik L. and Lesek F., Collect. Czech. Chem. Commun., 47, 1686 (1982).