Analysis of the Absorption Spectrum of U3+ Doped YCl3 Single Crystals

• Autorzy: Sobczyk M. , Drożdżyński J. , Karbowiak M.
• Języki publikacji: EN

Abstrakty

EN

Low-temperature emission and polarized absorption spectra of U3+ ions diluted in YCl3 host single crystals have been recorded in the 4000-50000 cm-1 spec tral range. The point symmetry of the doped U3+ ions has been assumed to be octahedral. 29 ex perimental crystal-field levels were fitted to seven parameters of a semi-empirical Hamiltonian represent ing the combined atomic, and one-electron crystal field operators, with arms deviations of 49 cm-1.

Słowa kluczowe

EN

uranium(3+); U3+:YCl3; single crystals; absorption spectrum; crystal-field parameters

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2005
• Tom: Vol. 79 / nr 11
• Strony: 1805--1811
• Opis fizyczny: Bibliogr. 9 poz., rys.

Twórcy

autor

Sobczyk M.

• Faculty of Chemistry, University of Wrocław, ul. F. Joliot-Curie 14, 50-383 Wrocław, Poland

autor

Drożdżyński J.

• Faculty of Chemistry, University of Wrocław, ul. F. Joliot-Curie 14, 50-383 Wrocław, Poland

autor

Karbowiak M.

• Faculty of Chemistry, University of Wrocław, ul. F. Joliot-Curie 14, 50-383 Wrocław, Poland

Bibliografia

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