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Synthesis, Characterization and Antimicrobial Activities of Some Metal Complexes with N'-(2-Chloro-benzoyl)thiourea Ligands: The Crystal Structure of fac-[CoL3] and cis-[PdL2]

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
N,N-dimethyl-N'-(2-chloro-benzoyl)thiourea (L1H) and N-pyrrolidine-N'-(2-chlorobenzoyl) thiourea (L2H) and their Ni(II), Cu(II), Zn(II), Pt(II), Pd(II) and Co(III) complexes. The structure of the prepared compounds was investigated by using elemental analyses, IR, 1H-NMR, UV-Vis, mass spectra and magnetic susceptibility. The prepared compounds were screened for their in vitro antibacterial and antifungal activities. All compounds showed antimicrobial activity, however, the antibacterial efficacy is better than antifungal activity. Molecular structures of Co(L1)3 and Pd(L1)2 were determined by single crystal X-ray diffraction methods. The ligands coordinate to Ni(II), Cu(II), Zn(II), Pt(II) and Pd(II) in a bidentate manner yielding essentially neutral complexes of the type ML2. The coordination polyhedra around the Co(III) ion are distorted octahedra.
Słowa kluczowe
Rocznik
Strony
1615--1626
Opis fizyczny
Bibliogr. 38 poz., rys.
Twórcy
autor
  • Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin 33343, Turkey
autor
  • Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin 33343, Turkey
autor
  • Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin 33343, Turkey
autor
  • Department of Chemistry, University of Paderborn, Paderborn, Germany
autor
  • Department of Microbiology, Faculty of Medicine, Mustafa Kemal University, Hatay, Turkey
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ3-0002-0176
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