Synthesis, Characterization and Antimicrobial Activities of Some Metal Complexes with N'-(2-Chloro-benzoyl)thiourea Ligands: The Crystal Structure of fac-[CoL3] and cis-[PdL2]

• Autorzy: Emen M. , Arslan H. , Külcü N. , Flörke U. , Duran N.
• Języki publikacji: EN

Abstrakty

EN

N,N-dimethyl-N'-(2-chloro-benzoyl)thiourea (L1H) and N-pyrrolidine-N'-(2-chlorobenzoyl) thiourea (L2H) and their Ni(II), Cu(II), Zn(II), Pt(II), Pd(II) and Co(III) complexes. The structure of the prepared compounds was investigated by using elemental analyses, IR, 1H-NMR, UV-Vis, mass spectra and magnetic susceptibility. The prepared compounds were screened for their in vitro antibacterial and antifungal activities. All compounds showed antimicrobial activity, however, the antibacterial efficacy is better than antifungal activity. Molecular structures of Co(L1)3 and Pd(L1)2 were determined by single crystal X-ray diffraction methods. The ligands coordinate to Ni(II), Cu(II), Zn(II), Pt(II) and Pd(II) in a bidentate manner yielding essentially neutral complexes of the type ML2. The coordination polyhedra around the Co(III) ion are distorted octahedra.

Słowa kluczowe

EN

thioureas; synthesis; X-ray structure

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2005
• Tom: Vol. 79 / nr 10
• Strony: 1615--1626
• Opis fizyczny: Bibliogr. 38 poz., rys.

Twórcy

autor

Emen M.

• Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin 33343, Turkey

autor

Arslan H.

• Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin 33343, Turkey

autor

Külcü N.

• Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin 33343, Turkey

autor

Flörke U.

• Department of Chemistry, University of Paderborn, Paderborn, Germany

autor

Duran N.

• Department of Microbiology, Faculty of Medicine, Mustafa Kemal University, Hatay, Turkey

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