Electrooxidative Conversion of Dibenzoylbenzene Dihydrazones into the Coreesponding Bis-Diazo Compounds and Bis-Dimethyl Acetals

• Autorzy: Okimoto M. , Numata K. , Takahashi Y.
• Języki publikacji: EN

Abstrakty

EN

Several dibenzoylbenzene dihydrazones were electrochemically oxidized into the corresponding bis-dimethyl acetals in a methanolic solution containing sodium methoxide and catalytic amount of KI. During electrolysis, the anolyte exhibited a characteristic deep purple, which strongly suggested that formation of a diazo compound as an intermediate. Interestingly, some of the diazo compounds could be isolated directly from the anolyte

Słowa kluczowe

EN

electrooxidation; dibenzoylbenzene dihydrazones

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2005
• Tom: Vol. 79 / nr 9
• Strony: 1477--1482
• Opis fizyczny: Bibliogr. 23 poz., rys.

Twórcy

autor

Okimoto M.

• Department of Applied and Environmental Chemistry, Kitami Institute of Technology, Koen-cyo 165, Kitami, Hokkaido 090-8507, Japan

autor

Numata K.

• Department of Applied and Environmental Chemistry, Kitami Institute of Technology, Koen-cyo 165, Kitami, Hokkaido 090-8507, Japan

autor

Takahashi Y.

• Department of Applied and Environmental Chemistry, Kitami Institute of Technology, Koen-cyo 165, Kitami, Hokkaido 090-8507, Japan

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