Trifluoromethylation of Carbonyl Compounds with Trifluoromethyltrimethylsilane (Ruppert Reagent) Promoted by Triphenyldifluorostannates

• Autorzy: Borkin D. , Loska R. , Mąkosza M.
• Języki publikacji: EN

Abstrakty

EN

Nucleophilic trifluoromethylation of aromatic aldehydes and ketones with trifluoromethyltrimethylsilane is initiated with KF/n-Bu3MeN+HSO4 /Ph3SnF cocatalytic system in CH2Cl2 or with K[Ph3SnF2] in DMF.

Słowa kluczowe

EN

organofluorine compounds; tin; hypervalent compounds; phase-transfer catalysis; fluorides

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2005
• Tom: Vol. 79 / nr 7
• Strony: 1187--1191
• Opis fizyczny: Bibliogr. 25 poz., rys.

Twórcy

autor

Borkin D.

• Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warszawa 42, POB 58, Poland

autor

Loska R.

• Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warszawa 42, POB 58, Poland

autor

Mąkosza M.

• Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warszawa 42, POB 58, Poland

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