Lactones 17. Synthesis of Bicyclic Lactones with the Methyl- or gem-Dimethylcyclopropane System

• Autorzy: Obara R. , Szumny A. , Żołnierczyk A. , Olejniczak T. , Białońska A. , Ciunik Z. , Wawrzeńczyk C.
• Języki publikacji: EN

Abstrakty

EN

A new method of synthesis of bicyclic gamma-lactones with the methyl- or gem-dimethylcyclopropane system from gamma,delta unsaturated esters is described. The reaction of gamma-halo delta- lactones with DBU is the key step of this synthesis. The mechanism of the dehydrohalogenation- cyclization process of gamma-halo-delta-lactones is proposed. The structures of products were confirmed by both spectroscopic and crystallographic methods.

Słowa kluczowe

EN

gamma-halo-delta-lactones; delta-halo-gamma-lactones; cyclization; DBU; elimination

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2005
• Tom: Vol. 79 / nr 6
• Strony: 981--993
• Opis fizyczny: Bibliogr. 30 poz., rys.

Twórcy

autor

Obara R.

• Institute of Chemistry, Świętokrzyska Academy, Chęcińska 5, PL-25-020 Kielce, Poland

autor

Szumny A.

• Department of Chemistry, Agricultural University, Norwida 25, PL-50-375 Wrocław

autor

Żołnierczyk A.

• Department of Chemistry, Agricultural University, Norwida 25, PL-50-375 Wrocław

autor

Olejniczak T.

• Department of Chemistry, Agricultural University, Norwida 25, PL-50-375 Wrocław

autor

Białońska A.

• Faculty of Chemistry, University of Wrocław, F. Joliot-Curie 14, PL-50-383 Wrocław, Poland

autor

Ciunik Z.

• Faculty of Chemistry, University of Wrocław, F. Joliot-Curie 14, PL-50-383 Wrocław, Poland

autor

Wawrzeńczyk C.

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