Synthesis and Structure of Spirocyclic Tetrahydrothiophene Derivatives Bearing a 'Cage' Residue

• Autorzy: Romański J. , Mlostoń G. , Linden A. , Heimgartner H.
• Języki publikacji: EN

Abstrakty

EN

Trapping of the thiocarbonyl S-methanide 4 with tetracyanoethene and N-methylmaleimide led to the [3+2]-cycloadducts 11 and 12, respectively. The structures of these cycloadducts were established by X-ray crystallography. The 1,3-dipole 4 has been generated by thermal decomposition of the corresponding 2,5-dihydro-1,3,4-thiadiazole 2, which was prepared by the 1,3-dipolar cycloaddition of diazomethane with thioketone 1.

Słowa kluczowe

EN

thiocarbonyl ylides; 1,3-dipolar cycloadditions; tetrahydrothiophenes; 2,5-dihydro-1,3,4-thiadiazoles; polycyclic compounds; crystal structure

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2005
• Tom: Vol. 79 / nr 6
• Strony: 973--979
• Opis fizyczny: Bibliogr. 24 poz., rys.

Twórcy

autor

Romański J.

• Section of Heteroorganic Compounds, University of Łódź, Narutowicza 68, PL-90-136 Łódź, Poland

autor

Mlostoń G.

• Section of Heteroorganic Compounds, University of Łódź, Narutowicza 68, PL-90-136 Łódź, Poland

autor

Linden A.

• Institute of Organic Chemistry, University of Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland

autor

Heimgartner H.

• Institute of Organic Chemistry, University of Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland

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