Hydrogen Peroxide Oxidation of Mono- and Disubstituted Alkylarenes Catalyzed by Dinuclear CoIII-CuII Macrocyclic Complex

• Autorzy: Golchoubian H. , Ghaziani A.
• Języki publikacji: EN

Abstrakty

EN

C-H oxidation of anthracene and eight other alkylarenes with binuclear macrocyclic complex of CoIII-CuII as a catalyst in the presence of 30% aqueous hydrogen peroxide to the corresponding carbonyl compounds were studied. The oxidation took place selectively at the benzylic C-H bond and no oxidation was observed in aromatic ring. The reaction is simple, clean and high yielding and generates water as the only by-product.

Słowa kluczowe

EN

monosubstituted arenes; disubstituted arenes; oxidation; hydrogen peroxide; catalyst; selective oxidation; binuclear macrocyclic complex

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2005
• Tom: Vol. 79 / nr 5
• Strony: 825--830
• Opis fizyczny: Bibliogr. 22 poz., rys.

Twórcy

autor

Golchoubian H.

• Department of Chemistry, University of Mazandaran, P.O.Box 453, Babolsar, Iran

autor

Ghaziani A.

• Department of Chemistry, University of Tehran, Tehran, Iran

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