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Nickel(II) Dithiocarbamates with AsI3 and SbI3 as Mixed Ligands

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Ni(II) dithiocarbamates with AsI3 or SbI3 as ligands of the composition [Ni(hmidtc)2(AsI3)] (1), [Ni(bzbutdtc)2(AsI3)] (2), [Ni(bzbutdtc)2(SbI3)]_2CHCl3 (3), [Ni(bz2dtc)2(AsI3)] (4), [Ni(bz2dtc)2(SbI3)]_CS2 (5), [Ni(hmidtc)2(AsI3)2]_CHCl3 (6), [Ni(hmidtc)2(SbI3)2] (7) and [Ni(cetdtc)2(AsI3)2] (8), (hmidtc = hexamethyleneiminedithiocarbamate, bzbutdtc = benzylbutyldithiocarbamate, bz2dtc = dibenzyldithiocarbamate, cetdtc = cyclohexylethyldithiocarbamate, dtc = S2CN-) have been synthesized. The complexes have been characterized by elemental analyses, thermal analysis, IR and UV/VIS spectroscopies, magnetochemical and conductivity measurements as square-pyramidal (1-5) and octahedral (6-8) complexes. X-ray analysis of [Ni(bz2dtc)2(AsI3)] and [Ni(bz2dtc)2(SbI3)]_CS2 confirmed square-pyramidal arrangement around nickel in both complexes with the NiS4As and NiS4Sb chromophore, respectively.
Słowa kluczowe
Rocznik
Strony
637--644
Opis fizyczny
Bibliogr. 26 poz., rys.
Twórcy
autor
  • Department of Inorganic Chemistry, Palacký University, Křízkovského 10, CZ-771 47 Olomouc, Czech Republic
  • Department of Inorganic Chemistry, Palacký University, Křízkovského 10, CZ-771 47 Olomouc, Czech Republic
  • Department of Inorganic Chemistry, Palacký University, Křízkovského 10, CZ-771 47 Olomouc, Czech Republic
  • Department of Inorganic Chemistry, Palacký University, Křízkovského 10, CZ-771 47 Olomouc, Czech Republic
autor
  • Department of Inorganic Chemistry, Palacký University, Křízkovského 10, CZ-771 47 Olomouc, Czech Republic
autor
  • Department of Inorganic Chemistry, Palacký University, Křízkovského 10, CZ-771 47 Olomouc, Czech Republic
  • Department of Inorganic Chemistry, Palacký University, Křízkovského 10, CZ-771 47 Olomouc, Czech Republic
Bibliografia
  • 1.Coucouvanis D., Progress in Inorganic Chemistry, Edited by S.J. Lippard, Interscience Publishers, New York, 1970, p. 233.
  • 2.Ali B.F., Al-Akramawi W.S, Al-Obaidi K.H. and Al-Karboli A.S., Thermochim. Acta, (2004), in press.
  • 3.Willemse J., Cras J.A., Bosnian W.P. and Steggerda J.J., Recueil. J. Royal Netherlands Chem. Soc.. 99. 65 (1980).
  • 4.Brauer G., Handbuch der Präparativen Anorganischen Chemie, I. Band, F. Enke Verlag, Stuttgart 1960, p. 533, 546.
  • 5.Přibil R., Komplexometricke titrate, SNTL, Praha 1955, p. 22.
  • 6.Jurček M., Organicka analyza II, ČSAV, Praha 1957, p. 140.
  • 7.Gmelins Handbuch der Anorganischen Chemie. Nickel, Teil C, Lief 2, Verlag Chemie, GmbH, Weinheim 1969, p. 997.
  • 8.Husärek J., unpublished results
  • 9. Cambi L. and Szegö L., Ber: Deut. Client. Ges., 64. 2594 (1931).
  • 10.Sheldrick G.M., SIIELXS-97; Enhanced version of SIIELX-S, Acta Cryst., A46. 467 (1990).
  • 11.Sheldrick G.M., SHELXL-97. Program for crystal structure refinement. University of Göttingen, 1997.
  • 12.Walker N. and Stuart D., Acta Cryst., A39, 158 (1983).
  • 13.Nardelli M., PARST 95, J. Appl. Cryst., 28, 659 (1995).
  • 14.Addison AAV., Rao T.N., Reedijk J., van Rijn J. and Verschoor G. C.,.J. Chem. Soc.. Dalton Trans., 1349 (1984).
  • 15.Lide D.R. (Ed.), Handbook of Chemistry and Physics, 73lJ Edit., CRC Press Boca Raton, FL 1992.
  • 16.Ballester L., Gutierrez A., Perpinan M.F. and Ruiz-Valero C., Polyhedron, 15, 1103 (1996).
  • 17.Nejding A.B., Magnetokhimija kompleksnych soyedinenij perekhodnykh metallov, Izd. Mir, Moscow 1970. p. 174.
  • 18.Geary W.J., Coord. Client. Rev., 7, 81 (1971).
  • 19.Lever A.B.P., Inorganic Electronic Spectroscopy, Elsevier, Amsterdam 1984, p. 521.
  • 20.Boudreaux E.A. and Mulay L.N., Theory and Application of Molecular Paramagnetism, Wiley, New York 1976, p. 491.
  • 21.Bosnich B., Bramley R., Nyholm R.S. and Tobe M.L., J. Am. Client. Soc.. 88, 3926 (1966).
  • 22.Tsipis C.A., Kessissoglou D.P. and Katsoulos G.A., Chim. Chron., New Series, 14. 195 (1985).
  • 23.Shen H.Y, Liao D.Z., Jiang Z.H. and Yan S.P., Trans. Met. Chem., 24, 581 (1999).
  • 24.Pilojan G.O and Novikova O.S., Zh. Neorg. Khint., 12, 602 (1967).
  • 25.Bede ZDS Search/Match for Windows, Ver. 4.53, (2000). Bede Scientific Instruments Ltd., Durham, United Kingdom.
  • 26.PDF-2 Database Sts 1-47, (1997). ICDD. 12 Campus Boulevard, Newtown Square, Pennsylvania 19073-3273, USA.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ3-0002-0072
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